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Preparation of porous mullite bodies

机译:制备莫来石多孔体

摘要

Porous sintered ceramic materials having mullite as its primary phase and a method for producing them are disclosed. The method comprises preparing a plasticizable raw material mixture comprised, by weight, of 75 to 99% pre-reacted mullite powder, and 1.0 to 25% of a water-swelling clay, adding an organic binder system to the mixture and mixing the mixture to form an extrudable mixture, and extruding the mixture to form a substrate of the desired configuration. The green body is dried and fired for a time and at temperature sufficient to form a sintered mullite structure having a narrow through-pore size distribution comprised of pores exhibiting an average intrusion-pore size of between about 2-15 µm, and a total intrusion porosity, as measured by Hg intrusion method, of at least 30%. Inclusion of an amount of alumina or an alumina-yielding precursor in the method results in the formation of a sintered mullite structure exhibiting an acid/base exposure strength loss of less than about 20%.
机译:本发明公开了以莫来石为主要相的多孔质烧结陶瓷材料及其制造方法。该方法包括制备可塑的原材料混合物,该混合物包括按重量计75%至99%的预反应的莫来石粉末和1.0%至25%的水溶胀性粘土,向该混合物中添加有机粘合剂体系并将该混合物混合至形成可挤出的混合物,并将混合物挤出以形成所需构型的基材。将生坯干燥并烧制一段时间,并在足以形成具有窄通孔尺寸分布的莫来石结构的温度下烧结,该莫来石结构的通孔尺寸分布较窄,该孔的平均侵入孔尺寸约为2-15 µm,总侵入通过汞侵入法测得的孔隙率至少为30%。在该方法中包括一定量的氧化铝或产生氧化铝的前体导致形成了显示出酸/碱暴露强度损失小于约20%的烧结莫来石结构。

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