POSITION-SELECTIVE OXIDATION CATALYST OF ADAMANTANE COMPRISING PORPHYRIN METAL COMPLEX HAVING IMIDAZOLYL GROUP AND METHOD FOR POSITION-SELECTIVE OXIDATION OF ADAMANTANE USING IT

摘要

PROBLEM TO BE SOLVED: To provide a catalyst that can oxidize adamantane position-selectively and a method for position-selective oxidation of adamantane using it.;SOLUTION: The position-selective oxidation catalyst of adamantane comprises a porphyrin metal complex having imidazolyl group represented by formula (1), wherein, M⁺ is an ion of a metal atom at the center of a porphyrin ring; R₁ is a group that can be substituted by a hydrogen atom or a porphyrin ring and plural R₁s may be each the same or different; Im is an imidazolyl group represented by Im₁ or Im₂ in the formula 2 (wherein, R₂ is an alkyl group or a hydrogen atom; X^- is a stable counter anion).;COPYRIGHT: (C)2004,JPO&NCIPI