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Method for producing current collector for lead-acid battery and positive electrode plate for lead-acid battery

机译:铅酸电池集电体的制造方法和铅酸电池正极板

摘要

PURPOSE:To prevent the fall out of the active material from a collector, and to securely prevent the corrosion of the grain interface of the crystal by forming a film, which is made of compound oxide, only on the crystal grain interface of the surface of a collector for lead-acid battery. CONSTITUTION:A collector element material formed of a grid body, which is made of lead alloy containing Sr or the like, is manufactured, and it is heated so that Sr is deflected by the interface 3a of crystal grains 3 of the collector element material, and a collector 1 for lead acid battery is thereby manufactured. This collector 1 is filled with the active material paste, and aging and drying are performed so as to form an active material layer 2, which is mainly composed of PbO2, on the collector 1. After the chemical conversion treatment is performed to the collector 1 formed with the active material layer 2, drying is performed, and PbO2 of the surface part 1a of the collector 1 and Sr of the crystal grain interface 3a are made to react with each other. A film 4 made of perovskite type plumbate, which is composed of SrPbO3, is formed on the only crystal grain interface 3a of the surface 1a of the collector 1 so as to finish a positive plate.
机译:目的:为了防止活性物质从集电体上掉下来,并仅在氧化锌表面的晶粒界面上形成由复合氧化物制成的膜,从而可靠地防止晶体晶粒界面的腐蚀。铅酸电池的集电器。组成:制造由格栅体形成的集电体元素材料,该材料由包含Sr等的铅合金制成,并被加热,使Sr被集电体元素材料的晶粒3a的界面3a偏转,从而制造铅蓄电池的集电体1。在集电体1中填充活性物质糊剂,进行老化和干燥,从而在集电体1上形成以PbO 2为主成分的活性物质层2。对集电体1进行化学转化处理后在形成有活性物质层2的情况下,进行干燥,使集电体1的表面部分1a的PbO 2与晶粒界面3a的Sr反应。在集电体1的表面1a的唯一的晶粒界面3a上形成由SrPbO 3构成的钙钛矿型铅酸盐制成的膜4,以完成正极板。

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