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User- and eco-friendly hypervalent iodine reagent and method of synthesis
User- and eco-friendly hypervalent iodine reagent and method of synthesis
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机译:用户和环境友好的高价碘试剂及其合成方法
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摘要
The present invention is a user- and eco-friendly hypervalent iodine reagent (mIBX) capable of selectively oxidizing allylic and benzylic alcohols in water and other eco-friendly solvents and having generally the following structure: chemistry chemdraw filechemistry mol file;Allylic and benzylic alcohols are cleanly oxidized to the corresponding carbonyl compounds in water or water-THF mixtures, or other mixtures, using a water-soluble o-iodoxybenzoic acid derivative of the present invention.
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机译:本发明是用户和环境友好的高价碘试剂(mIBX),其能够在水和其他生态友好溶剂中选择性氧化烯丙基和苄基醇,并且通常具有以下结构: <图像文件=“ US20040030187A1-20040212-C00001.GIF” he =“ 65.9988” id =“ EMI-C00001” imgContent =“ undefined” imgFormat =“ GIF” wi =“ 59.05305“ /> 化学化学绘图文件 ExternalFileRef> 化学mol文件 ExternalFileRef> Chemistry>;使用水溶性的邻-碘氧苯甲酸衍生物,在水或水-THF混合物或其他混合物中,将烯丙醇和苯甲醇干净地氧化为相应的羰基化合物本发明。
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