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Dodecahydrate of (diethylene-triamine-penta-acetato)bismuthate(III) of hexaaminecobalt(III) as dielectric material

机译:六胺钴(III)的(二亚乙基三胺-五乙酰基)铋(III)的十二水合物作为介电材料

摘要

The invention relates to the chemistry of heterometallic coordinative compounds, namely to [Co(NH3)6]2[Bi(DTPA)]3.12H2O, where H5DTPA=(HO2CCH2)2N(CH2)2N(CH2 CO2H) (CH2)2N(CH2CO2H)2. Such complex possesses a high specific resistance and may be used in the electric engineering. Summary of the invention consists in obtaining the dodecahydrate of (diethylene-triamine-penta-acetato)bismuthate(III) of hexaaminecobalt(III) of the formula: CHFORMas dielectric material. The result of the invention consists in the synthesis of heterometallic coordinative compound, having the specific resistance of 11...45 times higher than of its structural analogues.Claims: 2
机译:本发明涉及杂金属配位化合物的化学,即[Co(NH3)6] 2 [Bi(DTPA)] 3.12H2O,其中H5DTPA =(HO2CCH2)2N(CH2)2N(CH2CO2H)(CH2)2N( CH2CO2H)2。这种配合物具有高的电阻率,可用于电气工程中。发明内容本发明在于获得式(CHFORM)的六胺钴(III)的(二亚乙基三胺-五乙酸-乙酰)铋(III)的十二水合物作为介电材料。本发明的结果在于合成异金属配位化合物,其比电阻是其结构类似物的11 ... 45倍。

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