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FOAMS COMPOSED OF WATER-ABSORBING POLYMERS AND PREPARATION AND USE THEREOF

机译:吸水性聚合物组成的泡沫塑料及其制备和使用

摘要

Foams composed of water-absorbing basic polymers and preparation and use thereofAbstractFoams composed of water-absorbing basic polymers, obtainable by(I) foaming a crosslinkable aqueous mixture including(a) at least one basic polymer whose basic groups haveoptionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant,(d) optionally at least one solubilizer,(e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and(f) optionally particulate water-absorbing acidic polymers,by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and(II)crosslinking the foamed mixture to form a hydrogel foam andif applicable adjusting the water content of the polymer foam to 1-60% by weight.Preparation of the foams by application of the abovementioned measures (I) and (II) and use of the thus obtainable foams in hygiene articles to absorb body fluids, in dressing material to cover wounds, as a sealing material, as a packaging material, as a soil improver, as a soil substitute, to dewater sludges, toabsorb aqueous acidic wastes, to thicken waterborne paints or coatings in the course of disposing of residual quantities thereof, to deaater water-containing oils or hydrocarbons or as a material for filters in ventilation systems.
机译:由吸水性基础聚合物组成的泡沫及其制备及其用途抽象由吸水性基础聚合物组成的泡沫,可通过以下方法获得(I)发泡可交联的水性混合物,包括(a)至少一种碱性聚合物,其碱性基团具有可选地被中和,(b)至少一种交联剂,(c)至少一种表面活性剂,(d)任选地至少一种增溶剂,(e)可选的增稠剂,泡沫稳定剂,填料,纤维和/或细胞成核剂,和(f)可选的颗粒状吸水酸性聚合物,通过将对自由基呈惰性的气体溶解在可交联的水性混合物在2至400 bar,然后解压可交联将水性混合物调至大气压或分散细小气泡对自由基呈惰性的气体(II)使泡沫混合物交联以形成水凝胶泡沫,以及如果适用,调整聚合物泡沫的水含量至1-60重量%。通过应用上述方法制备泡沫措施(I)和(II)以及由此获得的泡沫在塑料中的使用卫生用品吸收体液,在敷料中覆盖伤口,作为密封材料,作为包装材料,如作为土壤替代品的土壤改良剂,用于脱水污泥,以吸收含水酸性废物,增稠水性涂料或剩余量处理过程中的涂料以消泡含水油或碳氢化合物或作为通风系统中过滤器的材料。

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