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POLYMERIC AMMONIUM AND OR PHOSPHONIUM SALTS HAVING ADDED .PI.-ELECTRONS AND HIGHER MOLECULAR WEIGHT AS ENHANCERS FOR CHEMILUMINESCENT SYSTEMS
POLYMERIC AMMONIUM AND OR PHOSPHONIUM SALTS HAVING ADDED .PI.-ELECTRONS AND HIGHER MOLECULAR WEIGHT AS ENHANCERS FOR CHEMILUMINESCENT SYSTEMS
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机译:聚铵和/或磷盐具有增加的PI电子和较高的分子量,可增强化学发光体系
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摘要
A compound for enhancing the light output of a chemiluminescent system and, in particular, a stabilized, triggerable 1,2-dioxetane, is obtained by reacting a polyvinylbenzyl halide and a bilinker with either a trisubstituted amine or trisubstituted phosphine. A fluorescent molecule may be attached to polymer along with the trisubstituted amine or trisubstituted phosphine. Also, the benzyl halide may be reacted with a .pi.-electron donor, such as a vinyl naphthalene or vinylanthracene to form a co-polymer which is polymerizable with the trisubstituted amine and/or trisubstituted phosphine. By controllin g the reaction parameters it is possible to obtain either a water-soluble or partial water soluble or insoluble compound crosslink polymer.
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