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METHOD OF SYNTHESIS OF 3D SILICON COLLOIDAL PHOTONIC CRYSTALS BY MICROMOLDING IN INVERSE SILICA OPAL (MISO)

机译:反相硅胶乳化微成型法合成3D硅胶体光子晶体的方法

摘要

A new type of synthetic silicon colloidal photonic colloidal crystal is described presenting a different topology than previously synthesised high refractive index contrast colloidal photonic crystals. It has been built using a new synthesis process based upon micromolding in inverse silica opals (MISO), where the micromold has a structure of interconnected air cavities in a silica matrix. By chemical vapour deposition of disilane within this micromold, a continuous and uniform silicon layer of controlled thickness is formed, which coats the walls of the silica matrix. Later, by dissolution of the starting silica micromold it is possible to oA new type of synthetic silicon colloidal photonic colloidal crystal is described presenting a different topology than previously synthesised high refractive index contrast colloidal photonic crystals. It has been built using a new synthesis process based upon micromolding in inverse silica opals (MISO), where the micromold has a structure of interconnected air cavities in a silica matrix. By chemical vapour deposition of disilane within this micromold, a continuous and uniform silicon layer of controlled thickness is formed, which coats the walls of the silica matrix. Later, by dissolution of the starting silica micromold it is possible to obtain a face centered cubic silicon colloidal photonic crystal with a topology never observed before and which presents a full photonic band gap, as indicated by theoretical photonic band structure calculations making them useful as optical components of envisioned all-optical microphotonic crystal devices, circuits, chips and computers.
机译:描述了一种新型的合成硅胶体光子胶体晶体,其呈现出与先前合成的高折射率对比胶体光子晶体不同的拓扑。它是使用一种新的合成工艺制造的,该工艺基于反二氧化硅蛋白石(MISO)中的微模,其中微模在二氧化硅基质中具有相互连接的气腔结构。通过在该微模具内进行乙硅烷的化学气相沉积,形成了厚度受控的连续且均匀的硅层,该硅层覆盖了二氧化硅基质的壁。后来,通过溶解起始二氧化硅微模,可以描述一种新型合成硅胶体光子胶体晶体,该晶体呈现出与先前合成的高折射率对比胶体光子晶体不同的拓扑结构。它是使用一种新的合成工艺制造的,该工艺基于反二氧化硅蛋白石(MISO)中的微模,其中微模在二氧化硅基质中具有相互连接的气腔结构。通过在该微模具内进行乙硅烷的化学气相沉积,形成了厚度受控的连续且均匀的硅层,该硅层覆盖了二氧化硅基质的壁。后来,通过溶解起始二氧化硅微模,可以得到面心立方立方硅胶体光子晶体,该晶体具有以前从未见过的拓扑结构,并呈现出完整的光子带隙,如理论上的光子能带结构计算所示,使其可用作光学设想的全光学微光子晶体器件,电路,芯片和计算机的组件。

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