首页> 外国专利> IMPROVEMENT OF FLUE GAS DESULFURIZATION GYPSUM-DEWATERING THROUGH CRYSTAL HABIT MODIFICATION BY CARBOXYLIC ACIDS

IMPROVEMENT OF FLUE GAS DESULFURIZATION GYPSUM-DEWATERING THROUGH CRYSTAL HABIT MODIFICATION BY CARBOXYLIC ACIDS

机译:通过羧酸修饰晶体习惯改善烟气脱硫石膏的能力

摘要

The present invention relates to dewatering of gypsum in flue gas desulfurization process based on a limestone forced oxidation technology. The dewatering is enabled and/or greatly enhanced by addition of carboxylic acids, preferably citric acid to the scrubbing slurry. It has been found that carboxylic acids serve as a gypsum crystal habit modifier during gypsum crystallization under forced oxidation. I has been found that under normal operating conditions, i.e. when no acid is added, gypsum crystals assume acicular (needle shape) habit and are difficult to dewater since they tend to retain mother liquor in the filter cake. In the presence of carboxylic acids, preferably citric acid, in scrubbing slurry gypsum crystals assume columnar (bulky) habit and can be readily dewatered in the centrifuge up to 90% solids & period. Also claimed is a device for dewatering gypsum and a cement plant comprising the device.
机译:本发明涉及一种基于石灰石强制氧化技术的烟气脱硫工艺中石膏的脱水。通过向洗涤淤浆中添加羧酸,优选柠檬酸,可以实现和/或大大增强脱水。已经发现,在强制氧化下的石膏结晶过程中,羧酸充当石膏的结晶习性改性剂。我发现在正常操作条件下,即不加酸时,石膏晶体呈针状(针状)的习惯,并且难以脱水,因为它们倾向于将母液保留在滤饼中。在洗涤浆液中,在羧酸(优选柠檬酸)的存在下,石膏晶体呈柱状(大块)习惯,在离心机中很容易脱水,固形物和周期高达90%。还要求保护一种用于使石膏脱水的设备和一种包括该设备的水泥厂。

著录项

  • 公开/公告号EP1472186A1

    专利类型

  • 公开/公告日2004-11-03

    原文格式PDF

  • 申请/专利权人 F.L. SMIDTH AIRTECH A/S;

    申请/专利号EP20030706321

  • 发明设计人 SCHULTZ ANDERS NIMGAARD;OLSEN PETER BO;

    申请日2003-02-07

  • 分类号C01F11/46;B01D53/73;C04B11/028;C04B11/26;B01D53/50;

  • 国家 EP

  • 入库时间 2022-08-21 22:51:00

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