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Alkali-clearable azo disperse dyes containing fluorosulfonyl group and preparing method thereof and dyeing method thereby

机译:含氟磺酰基的碱可清除偶氮分散染料及其制备方法和染色方法

摘要

PURPOSE: Provided are an azo-based alkali-clearable disperse dye containing fluorosulfone, which has clearing ability under a weak alkali condition after dyeing polyester fiber material, and a method for dyeing the polyester fiber material by using the alkali-clearable dispersing dye, which can omit a reduction clearing process. CONSTITUTION: The azo-based alkali-clearable disperse dye containing the fluorosulfone is an azobenzene-based monoazo compound(formula I) and is produced by coupling-reacting a diazonium salt(formula II) of an aromatic amine compound with an aromatic aniline-substituted monoazo intermediate compound (formula III) as a coupling component, wherein X1, X2, and X3 are hydrogen, nitro, chloro, bromo, or cyano, Y1 and Y2 are hydrogen, methyl, methoxy, or acetylamino, and R1 and R2 are substituted or unsubstituted alkyl. And the method for dyeing the polyester fiber material uses the disperse dye(formula I) and performs an alkali clearing instead of the reduction clearing.
机译:用途:提供一种含氟砜的偶氮类碱可清除分散染料,在对聚酯纤维材料进行染色后在弱碱条件下具有清除能力,以及使用该碱可清除分散染料对聚酯纤维材料进行染色的方法,可以省略减少清除过程。组成:含氟砜的偶氮基碱透明分散染料是偶氮苯基单偶氮化合物(式Ⅰ),是通过芳族胺化合物的重氮盐(式Ⅱ)与芳族苯胺取代的偶合盐反应制得的。作为偶合组分的单偶氮中间体化合物(式III),其中X1,X2和X3是氢,硝基,氯,溴或氰基,Y1和Y2是氢,甲基,甲氧基或乙酰氨基,并且R1和R2被取代或未取代的烷基。并且,对聚酯纤维材料进行染色的方法使用分散染料(式I),进行碱清除而不是还原清除。

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