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METHOD FOR ELIMINATING ORGANICS FROM WASTEWATER BY PHOTOCATALYTIC REACTION USING TRIVALENT IRON IONS

机译:三价铁离子的光催化反应从废水中去除有机物的方法

摘要

PURPOSE: A photocatalyst fixing method for improving photocatalyst stability and organic matter decomposition efficiency, a photocatalyst fixed by the photocatalyst fixing method, a method for eliminating organic matter in water using the fixed photocatalyst and a wastewater treatment system using the photocatalyst are provided. CONSTITUTION: The method for fixing photocatalyst comprises the step of fixing a photocatalyst using an inorganic binder, wherein the inorganic binder is an inorganic binder synthesized in the sol state in such a way that chemical resistance and bonding stability of the photochemical catalyst are improved. The method for preparing a titanium based inorganic binder in the sol state comprises the steps of synthesizing alcohol and titanium tetraisopropoxide in the composition volume ratio of 4.5 to 10.5% so that alcohol and titanium tetraisopropoxide are reacted for 0.2 to 1 hour; adding water and hydrochloric acid in the composition volume ratio of 0.5 to 1.5% to the reactant so that water and hydrochloric acid are reacted with the reactant; and forming an inorganic binder in the sol state by agitating the resulting material. The fixed photocatalyst having improved chemical resistance and bonding stability is characterized in that a photocatalyst having an average particle size of 5 to 50 nm is fixed to thickness of 1 to 20 m using the titanium based inorganic binder. The method for decomposing organics in wastewater comprises the step of efficiently decomposing organics in water by additionally adding trivalent iron ions (Fe¬3+) to the fixed photocatalyst. The organic matter treatment system comprises a photocatalyst member obtained by fixing the photocatalyst to a tube from which UV light is emitted using an inorganic binder; and a reactor containing a solution obtained by dissolving trivalent iron ions (Fe¬3+) into water.
机译:目的:提供一种用于提高光催化剂稳定性和有机物分解效率的光催化剂固定方法,通过该光催化剂固定方法固定的光催化剂,使用该固定的光催化剂去除水中有机物的方法以及使用该光催化剂的废水处理系统。组成:固定光催化剂的方法包括使用无机粘合剂固定光催化剂的步骤,其中无机粘合剂是以溶胶态合成的无机粘合剂,从而提高了光化学催化剂的耐化学性和粘合稳定性。制备溶胶态钛基无机粘合剂的方法包括以下步骤:合成醇与四异丙氧基钛的组成体积比为4.5至10.5%,以使醇与四异丙氧基钛反应0.2至1小时;向反应物中加入水和盐酸的组成体积比为0.5-1.5%,使水和盐酸与反应物反应。通过搅拌所得材料形成溶胶状态的无机粘合剂。具有改善的耐化学性和结合稳定性的固定的光催化剂的特征在于,使用钛基无机粘合剂将平均粒径为5至50nm的光催化剂固定为1至20m的厚度。用于分解废水中的有机物的方法包括通过向固定的光催化剂中另外添加三价铁离子(Fe 3+)来有效分解水中的有机物的步骤。该有机物处理系统包括通过将光催化剂固定到使用无机粘合剂从其发射紫外线的管上而获得的光催化剂部件;以及含有将三价铁离子(Fe 3+)溶解于水中而得到的溶液的反应器。

著录项

  • 公开/公告号KR20040079294A

    专利类型

  • 公开/公告日2004-09-14

    原文格式PDF

  • 申请/专利权人 SUNGKYUNKWAN UNIVERSITY;

    申请/专利号KR20030014449

  • 发明设计人 KIM BYEONG U;KIM MUN SEON;LEE JONG MIN;

    申请日2003-03-07

  • 分类号B01J37/02;

  • 国家 KR

  • 入库时间 2022-08-21 22:48:02

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