首页> 外国专利> Manufacturing method of E0 grade Melamine-Urea-Formaldehyde Resin(MUF) and adhesive for medium density fiber board by use of MDF Resin

Manufacturing method of E0 grade Melamine-Urea-Formaldehyde Resin(MUF) and adhesive for medium density fiber board by use of MDF Resin

机译:E0级中密度纤维板用三聚氰胺-尿素-甲醛树脂(MUF)和胶粘剂的制造方法

摘要

PURPOSE: A method for preparing a melamine-urea-formaldehyde resin and an adhesive for medium density fiberboard(MDF) using the resin are provided, to reduce the amount of the unreacted formaldehyde contained in the resin and the discharging amount of formaldehyde of MDF remarkably, and to improve the physical properties of MDF. CONSTITUTION: The method comprises the steps of polycondensing 0-10 wt% of melamine and formaldehyde(wherein the molar ratio of formaldehyde to an amino group is 1.3-2.2) at a pH 7.3-9.0 at a temperature of 80-95 deg.C; adding urea to the obtained one in the molar ratio of formaldehyde to an amino acid of 0.75-0.9 and polycondensing the mixture at a pH of 6.8-7.8 and at a temperature of 80-95 deg.C; adding an acidic catalyst to the product to make the pH be 4.0-6.8; adding an alkali catalyst to the product to neutralize the solution by making the pH be 6.0-8.0; adding urea to the obtained product in the molar ratio of formaldehyde to an amino acid of 0.53-0.62 and polycondensing the mixture; and adding urea to the obtained product in the molar ratio of formaldehyde to an amino acid of 0.38-0.46 and polycondensing the mixture, and aging it for 1-6 hours.
机译:目的:提供一种制备三聚氰胺-脲-甲醛树脂的方法和使用该树脂的中密度纤维板粘合剂,以显着减少树脂中未反应的甲醛量和MDF的甲醛排放量。 ,并改善MDF的物理性能。组成:该方法包括以下步骤:在80-95℃的温度下,将0-10 wt%的三聚氰胺和甲醛(其中甲醛与氨基的摩尔比为1.3-2.2)进行缩聚。 ;以甲醛与氨基酸的摩尔比为0.75-0.9的方式向所得到的脲中加入尿素,并在6.8-7.8的pH和80-95℃的温度下使混合物缩聚;向产品中加入酸性催化剂,使pH为4.0-6.8。向产物中加入碱催化剂,使pH为6.0-8.0,以中和溶液。以甲醛与氨基酸的摩尔比为0.53-0.62的方式向所得产物中加入尿素,并使混合物缩聚。然后,以甲醛与氨基酸的摩尔比为0.38〜0.46的方式,向所得产物中添加尿素,进行缩聚,使其熟化1〜6小时。

著录项

  • 公开/公告号KR100418515B1

    专利类型

  • 公开/公告日2004-02-11

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20010069570

  • 发明设计人 우영도;박명규;이윤일;

    申请日2001-11-08

  • 分类号C08G12/38;C08G12/32;C08G12/12;

  • 国家 KR

  • 入库时间 2022-08-21 22:47:31

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