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Functionalized initiators for the anionic polymerization, protected functionalized polymers, deblock either analogs thereof and method for producing the same.

机译:用于阴离子聚合的官能化的引发剂,被保护的官能化的聚合物使它们的类似物及其制备方法脱嵌段。

摘要

Connection, which is suitable as the electrophile, comprising the formula # # str1 # #: wherein:each x is independently a halogen,each z independently is a branched or straight-chain hydrocarbon - linking group, the 1 to 25 carbon atoms, optionally substituted by aryl or substituted aryl,each t is independently selected from the group consisting of oxygen, sulfur, nitrogen, and mixtures thereof,(A - r1R2R3) a protective group is, wherein each of a independent of one element selected from the group iva of the periodic table of elements, and r1, R2 and r3 each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, cycloalkyl or substituted cycloalkyl,R, r4 and r5 each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, cycloalkyl or substituted cycloalkyl,h 0 is, if t is oxygen or sulfur, and 1 is, if t is nitrogen,l is an integer..
机译:适于作为亲电子试剂的连接,包括式:#x str1##:其中:每个x独立为卤素,每个z独立为支链或直链烃基连接基团,含1至25个碳原子由芳基或取代的芳基取代的,每个t独立地选自氧,硫,氮及其混合物,(A-r 1 R 2 R < Sub> 3 )是一个保护基,其中每个独立于选自元素周期表的基团iva的一个元素,以及r 1 ,R 2 < / Sub>和r 3 各自独立地选自氢,烷基,取代的烷基,芳基,取代的芳基,环烷基或取代的环烷基,R,r 4 和r 5 各自独立地选自氢,烷基,取代的烷基,芳基,取代的芳基,环烷基或取代的环烷基,如果t为氧或磺基,则h 0为r,且1是,如果t是氮,则l是整数。

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