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Acrylonitrile - solutions of times imides

机译:丙烯腈-时代酰亚胺的解决方案

摘要

An acrylonitrile solution of maleimide manifesting transparency, precluding coloration and opacification during the course of handling, and excelling in stability, a method for the preparation of the acrylonitrile solution, and an acrylonitrile based copolymer obtained by using the acrylonitrile solution are provided.PPThe acrylonitrile solution of maleimide is such that, when it is subjected to a forced coloration test, the differences &Dgr;L, &Dgr;a, and &Dgr; b values (invariably as absolute values) each between L, a, and b values before and after the test are respectively not more than 5, not more than 5, and not more than 10. The acrylonitrile solution of maleimide is prepared by lowering the water content in the acrylonitrile solution to a level of not more than 0.1% by weight, or causing the acrylonitrile solution to permit coexistence therein of at least one member selected from the group consisting of alkyl-substituted hydroxybenzenes and hindered phenols and at least one member selected from the group consisting of phosphorous esters, phosphoric esters, phosphine, and phosphoric acid amides, or lowering the water content in the acrylonitrile solution to a level of not more than 0.3% by weight and causing the acrylonitrile solution to permit coexistence therein of at least one member selected from the group consisting of alkyl-substituted hydroxybenzenes, hindered phenols, phosphorous esters, phosphoric esters, phosphine, and phosphoric acid amides.
机译:提供了一种马来酰亚胺的丙烯腈溶液,该丙烯腈溶液显示透明性,在处理过程中不着色和不透明,并且稳定性优异,提供了该丙烯腈溶液的制备方法,以及使用该丙烯腈溶液获得的丙烯腈基共聚物。 & P&马来酰亚胺的丙烯腈溶液在进行强制着色试验时,其差&Dgr,L,d和在测试之前和之后的L,a和b值之间的b值(总是作为绝对值)分别不大于5,不大于5和不大于10。通过降低该值来制备马来酰亚胺的丙烯腈溶液。丙烯腈溶液中的水含量不超过0.1重量%,或使丙烯腈溶液在其中共存选自烷基取代的羟基苯和受阻酚中的至少一种和至少一种选自亚磷酸酯,磷酸酯,膦和磷酸酰胺,或将丙烯腈溶液中的水含量降低至不超过0.3重量%的水平,并使丙烯腈溶液在其中共存于选自烷基取代的羟基苯,受阻酚,亚磷酸酯,磷酸酯,膦和磷中的至少一种酸酰胺。

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