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Cleavable surfactants which may be useful in viscoelastic compositions for oil-field applications
Cleavable surfactants which may be useful in viscoelastic compositions for oil-field applications
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机译:可裂解的表面活性剂,可用于油田应用的粘弹性组合物中
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摘要
Cleavable surfactants of formulae 1, 2 or 3 in which R1 is an optionally unsaturated, optionally branched aliphatic chain of at least 18 carbon atoms, X is an OCO, CO2, NR7CO or CONR7 group, m is at least 1, Y is NR2R3R4, R2, R3, R4, R5, R6 and R7 are each independently H or a saturated aliphatic chain which is optionally substituted by one or more OH groups with the proviso that in compounds of formula 3 the R group linked to A-is not H. A- is a sulfonate or carboxylate anionic group, Z- is a monovalent or divalent anion and B+ is a monovalent cation or a proton. Surfactants of formula 1 in which X is OCO, R5 and R6 are each hydrogen, m is greater than or equal to 1 but less than 5 and Y+ is NR2R3R4 are specifically excluded, but examples of surfactants given are N,N-dimethyl N-ethyl glycine erucyl ester chloride and monooleyl succinic acid. The surfactants may be useful in the preparation of viscoelastic compositions for oil-field applications, especially for hydraulic fracturing of subterranean formations. They comprise a weak chemical bond which may be broken under appropriate conditions to produce oil- and water-soluble products which typically have no interfacial properties and surface activity compared with the original surfactant molecule.
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机译:式1、2或3的可裂解表面活性剂,其中R 1为至少18个碳原子的任选不饱和,任选支链的脂族链,X为OCO,CO 2,NR 7 CO或CONR 7基团,m为至少1,Y为NR 2 R 3 R 4, R 2,R 3,R 4,R 5,R 6和R 7各自独立地为H或饱和脂族链,其任选地被一个或多个OH基团取代,条件是在式3的化合物中,与A-连接的R基团不是H-A-为磺酸根或羧酸根阴离子基团,Z-为单价或二价阴离子,并且B +为单价阳离子或质子。特别排除其中X为OCO,R 5和R 6各自为氢,m大于或等于1但小于5且Y +为NR 2 R 3 R 4的式1表面活性剂,但给出的表面活性剂的实例为N,N-二甲基N-乙基甘氨酸芥酸酯氯化物和单油基琥珀酸。表面活性剂可用于制备用于油田应用的粘弹性组合物,特别是用于地下地层的水力压裂。它们包含弱的化学键,该弱的化学键在适当的条件下可被断裂以产生油溶性和水溶性产物,与原始的表面活性剂分子相比,该油溶性和水溶性产物通常不具有界面性质和表面活性。
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