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FLUOROUS AMIDE

机译:氟酰胺

摘要

PROBLEM TO BE SOLVED: To provide a fluorous amide (fluorous DMF) keeping the characteristic features of formamide and acetamide which are aprotic polar solvents having high functionality.;SOLUTION: The amide is expressed by formula (I), satisfies the requirements that (1) it is a substituted amide, (2) it has a fluorous tag, (3) it is liquid at a temperature (15-200°C) ordinarily used as a solvent and (4) it does not decompose at the above temperature, and is recoverable with a fluorous solvent and reusable. When the amide is used in combination with a fluorous catalyst, both substances can be recovered at the same time and reused. In the formula, R is methyl or ethyl; R' is H or methyl; Rf is a perfluoro-substituent; and n is 0-3.;COPYRIGHT: (C)2005,JPO&NCIPI
机译:解决的问题:提供一种氟酰胺(氟DMF)并保持甲酰胺和乙酰胺的特性,这是具有高官能度的非质子极性溶剂。解决方案:酰胺由式(I)表示,满足以下要求: )是取代的酰胺,(2)具有氟标签,(3)在通常用作溶剂的温度(15-20°C)下为液体,(4)在上述温度下不分解,并且可以用含氟溶剂回收并重复使用。当酰胺与氟催化剂结合使用时,两种物质可同时回收并重新使用。式中,R为甲基或乙基; R'是H或甲基; Rf是全氟取代基;且n为0-3 。;版权所有:(C)2005,JPO&NCIPI

著录项

  • 公开/公告号JP2005255546A

    专利类型

  • 公开/公告日2005-09-22

    原文格式PDF

  • 申请/专利权人 NOGUCHI INST;

    申请/专利号JP20040065754

  • 申请日2004-03-09

  • 分类号C07C233/13;C07C2/86;C07C15/54;

  • 国家 JP

  • 入库时间 2022-08-21 22:36:09

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