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Method for producing dielectric thin film with layered perovskite structure, dielectric thin film with layered perovskite structure and electronic component having dielectric thin film with layered perovskite structure

机译:具有层状钙钛矿结构的介电薄膜的制造方法,具有层状钙钛矿结构的介电薄膜和具有具有层状钙钛矿结构的介电薄膜的电子部件

摘要

PROBLEM TO BE SOLVED: To thermodynamically realize a layer-like structure in a non-balanced state, by stacking perovskite compound having nonstoichrometric composition on a desired substrate, and non-orderly and orderly stacking a perovskite structure layer which an oxygen octahedron shares an apex and a rock salt structure. SOLUTION: A generation device 1 splashes an exciting type and the like from a target 3 irradiating a laser beam and generates a thin film having a composition which is almost similar to the target 3 on a facing substrate for film forming 4. The target 3 is the sintered body of Ba1.2 TiO3.2 formed of A site excess, and it has a fine structure constituted of BaTiO3 particles having perovskite structure and secondary phase Ba2 TiO4 which is uniformly distributed in a grain boundary. Thus, a Bax TiO2+x dielectric thin film having the A site excess of a layer-like perovskite structure can be formed.
机译:解决的问题:为了热力学地在不平衡状态下实现层状结构,方法是将具有非化学计量组成的钙钛矿化合物堆叠在所需基板上,并无序和有序地堆叠氧八面体共有顶点的钙钛矿结构层。和盐岩结构。解决方案:产生装置1从被激光束照射的靶3溅出激发类型等,并在用于成膜的对向基板4上产生具有与靶3几乎相似的组成的薄膜。靶3为Ba1.2 TiO3.2的烧结体由过量的A位形成,并且具有由具有钙钛矿结构的BaTiO 3颗粒和均匀地分布在晶界中的第二相Ba 2 TiO 4构成的精细结构。因此,可以形成A位过量于层状钙钛矿结构的Bax TiO 2 + x介电薄膜。

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