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Film-forming resin composition and polyester film using silicon-containing polyester resin dispersible or soluble in water

机译:成膜树脂组合物和使用可分散或溶于水的含硅聚酯树脂的聚酯膜

摘要

PROBLEM TO BE SOLVED: To obtain a water-dispersible or water-soluble, silicon-contg. polyester resin excellent in slip properties, strengths, etc., by subjecting a dicarboxylic acid component, a glycol component, a water solubilizer, and a reactive silicone oil to polycondensation. SOLUTION: This polyester resin is obtd. by subjecting a dicarboxylic acid component (A) (e.g. terephthalic acid), a glycol component (B) (e.g. ethylene glycol), a water-solubilizer (C) (e.g. 5-sulfoisophthalic acid) in an amt. of 1-60mol% of the sum of components A and C, and a reactive silicone oil (D) capable of being condensed or polycondensed with components A, B, and C and in an amt. of 1-50wt.% of all the reactants to polycondensation. A pref. example of the silicone oil is one represented by formula I (wherein n is 1-50; X1 and X2 are each 1-8C alkyl, 6-14C aryl, or aralkyl; X3 and X4 are each a group represented by formula II, etc.; R1 to R4 are each H or alkyl; m is 1-10; p is 0-50; q is 0-30; and Y1 is H, OH, etc).
机译:要解决的问题:获得水分散性或水溶性的含硅化合物。通过使二羧酸成分,二醇成分,水增溶剂和反应性硅油缩聚,从而具有优异的滑动性,强度等的聚酯树脂。解决方案:该聚酯树脂是肥胖的。通过使二羧酸组分(A)(例如对苯二甲酸),二醇组分(B)(例如乙二醇),水增溶剂(C)(例如5-磺基间苯二甲酸)在氨气中经受。占组分A和C总和的1-60mol%,以及能够与组分A,B和C缩合或缩聚的反应性硅油(D)。 1-50wt。%的所有反应物缩聚。偏爱硅油的实例为由式I表示的硅油(其中n为1-50; X 1和X 2分别为1-8C烷基,6-14C芳基或芳烷基; X 3和X 3 4分别为式II等所表示的基团; R 1至R 4各自为H或烷基; m为1-10; p为0-50; q为0-30;和Y < 1>是H,OH等)。

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