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Method for separating and removing zinc from nickel sulfate solution

机译:从硫酸镍溶液中分离去除锌的方法

摘要

PROBLEM TO BE SOLVED: To provide a method for separating and removing zinc from an aqueous solution of nickel sulfate containing cobalt and zinc in which, by improving the conventional method where hydrogen sulfide is blown into the aqueous solution to selectively precipitate zinc sulfide, and zinc is separated and removed from the aqueous solution, zinc is almost perfectly separated and removed with hardly losing nickel and cobalt without using a pH conditioner for controlling the production reaction of precipitation. SOLUTION: In the above conventional method, (1) the concentration of zinc in the above aqueous solution is =0.5 g/l, (2) the pH of the aqueous solution is previously controlled to the range of 2.5 to 3.8, and (3) the ORP(oxidation-reduction potential) of the aqueous solution is controlled to the range of -260 to -120 mVvs.Ag/AgCl in accordance with the amount of hydrogen sulfide to be blown.
机译:解决的问题:提供一种从含有钴和锌的硫酸镍水溶液中分离和去除锌的方法,其中,通过改进将硫化氢吹入水溶液中以选择性地沉淀硫化锌和锌的常规方法,从水溶液中分离并除去锌,而无需使用pH调节剂来控制沉淀的生产反应,几乎可以完全分离锌并除去锌和钴,而几乎不损失镍和钴。解决方案:在上述常规方法中,(1)上述水溶液中锌的浓度<= 0.5 g / l,(2)预先将水溶液的pH值控制在2.5至3.8的范围内,以及( 3)根据要吹入的硫化氢的量,将水溶液的ORP(氧化还原电位)控制在-260〜-120mVvs.Ag / AgCl的范围内。

著录项

  • 公开/公告号JP3627641B2

    专利类型

  • 公开/公告日2005-03-09

    原文格式PDF

  • 申请/专利权人 住友金属鉱山株式会社;

    申请/专利号JP20000313046

  • 发明设计人 小林 宙;今村 正樹;

    申请日2000-10-13

  • 分类号C22B3/44;C01G9/08;C01G53/10;C22B19/20;C22B23/00;

  • 国家 JP

  • 入库时间 2022-08-21 22:26:23

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