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Method for producing allyl compound, and allyl compound produced thereby

机译:制备烯丙基化合物的方法以及由此制备的烯丙基化合物

摘要

A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with a nucleophilic agent in the presence of a catalyst containing at least one transitional metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having structures of the following formulae (I) to (III): embedded imagewherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an alkylene group which may have a substituent, an arylene group which may have a substituent, an alkylene-arylene group which may have a substituent or a diarylene group which may have a substituent.
机译:一种具有不同于烯丙基原料化合物的组成式的烯丙基化合物的制备方法,其包括在含有至少一种过渡金属化合物的催化剂存在下,使烯丙基原料化合物与亲核试剂反应。选自元素周期表第8至第10族的过渡金属和选自具有以下式(I)至(III)的结构的化合物中的至少一种二齿配位亚磷酸酯化合物: <图像alt =“嵌入的图像” file =“ US20050075518A1-20050407-C00001.GIF” he =“ 36.91mm” id =“ EMI-C00001” imgContent =“ chem” imgFormat =“ GIF” wi =“ 63.33mm” /> 其中A 1 至A 3 分别独立地为在邻位具有支链烷基的二亚芳基,R 1 至R 6 分别独立地是可具有取代基的烷基或可具有取代基的芳基(包括在环的上,下侧形成芳族6π电子云的杂环化合物),以下相同)和Z 1 至Z 3 分别独立地是可以具有取代基的亚烷基,可以具有取代基的亚芳基,可以具有取代基的亚烷基-亚芳基具有取代基或可以具有取代基的二亚芳基。

著录项

  • 公开/公告号US2005075518A1

    专利类型

  • 公开/公告日2005-04-07

    原文格式PDF

  • 申请/专利权人 MASAKI TAKAI;YOSHIYUKI TANAKA;

    申请/专利号US20030650697

  • 发明设计人 YOSHIYUKI TANAKA;MASAKI TAKAI;

    申请日2003-08-29

  • 分类号C07C41/06;

  • 国家 US

  • 入库时间 2022-08-21 22:21:30

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