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Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
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机译:用于生产光收集阵列的per-卟啉结构单元及其聚合物的合成
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摘要
The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:X1Xm+1)m (I)wherein m is at least 1; X1 is a charge separation group, and X2 through Xm+1 are chromophores. At least one of X2 through Xm+1 has at least one perylene group coupled thereto.
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机译:本发明提供了用于合成光收集阵列的方法,化合物和组合物,这些阵列包括:(a)包含第一电极的第一基底; (b)电耦合到所述第一电极的光收集棒的层,每个所述光收集棒包括式I的聚合物:<?in-line-formulae description =“在线表达式” end =“ lead”?> X 1 Sup>X m + 1 Sup>) m Sub>(I)<?in-line-formulae description =“在线公式” end =“ tail”?>其中m至少为1; X 1 Sup>是电荷分离基团,X 2 Sup>到X m + 1 Sup>是发色团。 X 2 Sup>至X m + 1 Sup>中的至少一个具有至少一个与之偶联的ylene基。
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