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Palladium-catalyzed cross-coupling of aryldiazonium salts with arylsilanes
Palladium-catalyzed cross-coupling of aryldiazonium salts with arylsilanes
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机译:钯催化的芳基重氮盐与芳基硅烷的交叉偶联
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摘要
A palladium catalyzed cross-coupling of aryldiazonium salts with organosilanes is disclosed. New reactions that are user friendly and environmentally friendly are now possible, including some reactions that could not be achieved using prior methods. The organosilanes that may be cross-coupled with aryldiazonium salts include, for example, Ar′—Si(L)3, where Ar′=aryl, and where L═CH3, OCH3, F, Cl, R, or OR.
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机译:公开了芳基重氮盐与有机硅烷的钯催化的交叉偶联。现在可以进行用户友好和环境友好的新反应,包括使用现有方法无法实现的一些反应。可以与芳基重氮盐交联的有机硅烷包括,例如,Ar'-Si(L) 3 Sub>,其中Ar'=芳基,以及其中L═CH 3 Sub >,OCH 3 Sub>,F,Cl,R或OR。
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