Compositions comprising a metal Complex ligand N - giver Tetra amido macrociclico as a Bleaching Catalyst

摘要

Compositions comprising a metal Complex - Tetra amido macrocyclic ligand N - giver as a catalyst of Laundering.It provides a composition for Bleaching laundry comprising: a) a complex of a metal ligand N - giver Tetra amido macrocyclic (preferably 5.6 - benzo - 3,8,11,13 tetraoxo 2,2,9,9,12,12 hexamethyl - - - - - - - tridecano Chemicals 1,4,7,10 cycle)And (b) an Enhancer that composition being substantially free of any aggregate of peroxygen Bleach or a peroxy Bleaching system based on peroxilos or generated.Claim 1: a Bleaching composition comprising a metal Complex;) - Tetra amido macrocyclic ligand N - giver, and (b) an Enhancer of detergency, Said composition being substantially free of any aggregate of peroxygen Bleach or a Bleaching system based on Peroxilos peroxy or generated.4: a Vindication of Laundering composition according to claim 1, wherein the metal - ligand is one that has the structure shown in the formula (1) wherein: B1, B3 and B4 each group represent a Bridge that has nodes that contain 0, 1 2 or 3 c for replacementGroup B2 and represents a Bridge that has at least a node that contains a C for replacement of such nodes, each containing a C (R), C (R1) (R2) or C (R) 2, each Substituent R is the same or different substituents R (i) is remaining, and selected from the group consisting of alkyd ILO, alquenilo, cicloalquenilo, cycloalkyl, aryl, alquinilo, alkylaryl, halogen, alkoxy,Phenoxy and combinations thereof, or (ii) form a benzene Ring substituted or unsubstituted c in which two nodes in the Ring Forming Unit B; M is a transition metal ion; l is an axial ligand; and q is an alkali metal counter ion or - or Tetra alkyl Ammonium tetra - FENI L phosphonium.