Complex of transition metal coordinated with a ligand macropoliciclico

摘要

Metal complex includes: (a) a transition metal atom selected from Mn (II) group,Mn (III)Mn (IV)MN (V),Faith (II),Faith (III),Faith (4)CO (I),Co (II)Co (III)Cr (II)Cr (III)Cr (IV)CR (V),Cr (VI)Page: 1Page: 1Page: 1Mo (IV)MO (V),Mo (VI)W (IV),W (V),W (VI),Pd (II)Ru (II)Ru (III)United Nations Industrial Development OrganizationAnd (b) a cross macrocyclic multi loop bridge, including: (1) at least four donation atoms; and (2) a functional group, including a cross bridge chain, connecting at least two non adjacent donation atoms. The donor atoms are covalently linked to coordinate with the transition metal; the cross bridge chain is composed of 2 to 5 atoms; the transition metal atoms are coordinated with the cross bridge macro multi cycle alliance. Transition metal complexes are part of an effective material oxidation catalysis system.