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A NOVEL PROCESS FOR THE ELIMINATION OF FREE FOR MALDEHYDE PRESENT IN LEATHER

机译:消除皮革中游离甲醛存在的新方法

摘要

A process for elimination of formaldehyde from leather has been developed wherein leather which is to be subjected to the treatment of formaldehyde or its derivatives during post tanning operations is rehydrated by conventional method and is then taken in 200 - 350% by volume of water based on the weight of the leather under consideration, pH of the bathe is adjusted in the range of 4 - 6.5 by known method and 8-16 times w/w of deformaldehyde agent on the total potential presence of free formaldehyde in the leather considering the present content of free formaldehyde as well as the formaldehyde derivatives, which are going to be added, during the subsequent operations, is added to the leather in dynamic condition either in the absence or presence of syntan or dye. Leather is treated with the deformaldehyde agent preferably in the presence of conventional fatliquor, the addition which may be either simultaneous with or preceding or succeeding the addition of the said agent. Finally the acidification is done by adjusting pH in the range of 2 - 4 and the resulting leather is washed in water by conventional method before it is taken out of the processing bath.
机译:已经开发了一种从皮革中消除甲醛的方法,其中将在鞣制后的工序中要进行甲醛或其衍生物处理的皮革通过常规方法再水化,然后以200-350%(体积)的水计,基于考虑到皮革的重量,通过已知方法将浴液的pH值调节在4-6.5的范围内,考虑到目前含量,皮革中游离甲醛的总潜在存在量为8-16倍w / w的脱甲醛剂在随后的操作过程中要加入的游离甲醛以及甲醛衍生物,在没有或没有合成鞣剂或染料的情况下,以动态条件添加到皮革中。皮革优选在常规加脂剂的存在下用脱甲醛试剂处理,添加可以在添加所述试剂的同时或之前或之后进行。最后,通过将pH调节在2-4范围内来进行酸化,并且在将其从处理浴中取出之前,通过常规方法将所得皮革用水洗涤。

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