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PROCEDURE FOR THE PREPARATION OF OPTICALLY PURE TETRAHYDROPTERINS AND OF THEIR DERIVATIVES, IN SPECIFIC OPTICALLY PURE TETRAHYDROPHOLIC ACID AND ITS DERIVATIVES, BY ESSENTIALLY SPECIFIC HYDROGENATION.
PROCEDURE FOR THE PREPARATION OF OPTICALLY PURE TETRAHYDROPTERINS AND OF THEIR DERIVATIVES, IN SPECIFIC OPTICALLY PURE TETRAHYDROPHOLIC ACID AND ITS DERIVATIVES, BY ESSENTIALLY SPECIFIC HYDROGENATION.
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机译:通过基本上特定的加氢制备特定的纯四氢磷酸及其衍生物中的纯四氢卟吩及其衍生物的方法。
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摘要
Process for the preparation of tetrahydropterin and tetrahydropterine derivatives by hydrogenation of pterine and of derivatives of pterine with hydrogen in the presence of a hydrogenation catalyst, characterized in that hydrogenation is carried out in a polar reaction medium and used as catalysts for hydrogenation d-8 metal complexes, soluble in the reaction medium, containing tertiary phosphines, tertiary phosphanes as ligands, bidentate ligands with tertiary amino groups and tertiary phosphino groups, or bidentate ligands with two tertiary phosphine groups, forming bidentate ligands with the atom metallic a ring of 5 to 10 members.
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