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PVC compositions stabilized thermally.

机译:PVC组合物热稳定。

摘要

Flexible PVC compositions exhibiting high thermal and oxidative stability, containing aminouracyls oligomeric and / or polymeric, characterized by the fact that the oligomeric and / or polymeric aminouracyls consist of: - a repetitive group of formula (I): * * (Formula) ** wherein: R is H, C1-C18 linear or branched, cycloalkyl C5-C8, aryl, aryl substituted with -OH or C1-C8 (= substituted aryl), arylalkyl, alkylaryl; R1 is H, - (C = O) C1-C12 linear or branched, - (C = O) -O-C1-C12 linear or branched, - (C = O) -phenyl, unsubstituted or substituted with -OH, C1-C8 linear or branched C1-C8 alkoxy; Z is O or S; - linking groups between the repetitive groups of formula (I) the same or different as: - (CR2R3) n- where R2, R3 may be the same or different and each independently of the other is -H, C1-C12 alkyl C linear or branched or cyclic and n is an integer equal to or greater than 2; or 3-methylene-3, 5, 5-yl-trimethylcyclohexan-1-, methylenebis (4ciclohexilo), methylenebis (3-cyclohexyl), 1, 4-phenylene, 1-methyl-2, 4-phenylene, 4, 4¿- diphenylene; - terminal groups as: H, C1-C18 linear or branched alkyl, C5-C8 alkyl, C3-C18, aryl, substituted aryl, arylalkyl, alkylaryl, hydroxyalkyl C1-C18 alkoxyalkyl, C2-C18 cycloalkoxyalkyl C6-C10, I alkoxyaryl C7-C14, C7-C14 aryloxyalkyl, C2-C8 alkylthioalkyl, C6-C10 cycloalkylthioalkyl, C7-C14 alkylthioaryl, C7-C14 arylthioalkyl, C1-C18 alkylamine, disubstituted with C1-C18 linear or branched alkyl.
机译:具有高热和氧化稳定性的柔性PVC组合物,包含低聚和/或聚合的氨基尿嘧啶,其特征在于低聚和/或聚合的氨基尿嘧啶由以下物质组成:-式(I)的重复基团:其中:R是H,C1-C18直链或支链,环烷基C5-C8,芳基,被-OH或C1-C8取代的芳基(=取代的芳基),芳基烷基,烷基芳基; R1是H,-(C = O)C1-C12直链或支链,-(C = O)-O-C1-C12直链或支链,-(C = O)-苯基,未取代或被-OH取代,C1 -C8直链或支链C1-C8烷氧基; Z为O或S; -式(I)的重复基团之间的连接基团相同或不同:-(CR2R3)n-其中R2,R3可以相同或不同,并且彼此独立地是-H,C1-C12烷基C线性或分支的或环状的,并且n是等于或大于2的整数;或3-亚甲基-3,5,5,5-基-三甲基环己-1-,亚甲基双(4-环己基),亚甲基双(3-环己基),1,4-亚苯基,1-甲基-2,4-亚苯基,4,4 -二亚苯基; -如下的末端基团:H,C 1 -C 18直链或支链烷基,C 5 -C 8烷基,C 3 -C 18,芳基,取代的芳基,芳基烷基,烷基芳基,羟烷基C 1 -C 18烷氧基烷基,C 2 -C 18环烷氧基烷基C 6 -C 10,I烷氧基芳基C 7 -C 14,C 7 -C 14芳氧基烷基,C 2 -C 8烷硫基烷基,C 6 -C 10环烷硫基烷基,C 7 -C 14烷硫基芳基,C 7 -C 14芳硫基烷基,C 1 -C 18烷基胺,其被C 1 -C 18直链或支链烷基二取代。

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