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METHOD FOR PRODUCING ALCOXYLATED CARBONYL COMPOUNDS BY AN ANODIC OXIDATION METHOD USING A CATHODIC COUPLED REACTION FOR ORGANIC SYNTHESIS
METHOD FOR PRODUCING ALCOXYLATED CARBONYL COMPOUNDS BY AN ANODIC OXIDATION METHOD USING A CATHODIC COUPLED REACTION FOR ORGANIC SYNTHESIS
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机译:阴极偶联反应通过阳极氧化-阳极氧化法制备羰基化羰基化合物的方法
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摘要
A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R1aR2C(OR3)b wherein R1, R2 represent hydrogen or C1-C6-alkyl, R3 independently means C1-C6-alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R4, R5, R6, R7 represent hydrogen or C1-C6-alkyl, R5, R6 represent C1-C6-alkyl or C1-C6-alcoxy, in the presence of a C1-C6-alkyl alcohol (compounds III). A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C1-C6-alkyl alcohols.
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