首页> 外国专利> METHOD FOR PREPARING EXPANSION CARBON FROM WASTE ION EXCHANGE RESIN WITHOUT GRAPHITE AND SULFURIC ACID TO RECYCLE WASTE ION EXCHANGE RESIN TO BE DISUSED

METHOD FOR PREPARING EXPANSION CARBON FROM WASTE ION EXCHANGE RESIN WITHOUT GRAPHITE AND SULFURIC ACID TO RECYCLE WASTE ION EXCHANGE RESIN TO BE DISUSED

机译:由无石墨和硫酸的废离子交换树脂制备可循环利用的废碳交换方法

摘要

PURPOSE: To a preparation method of expansion carbon from waste ion exchange resin, wherein the waste ion exchange resin is recycled, and the expansion carbon is prepared without graphite and sulfuric acid by preparing the expansion carbon from waste ion exchange resin disused after being used in removal of inorganic matter contained in water. CONSTITUTION: The preparation method of expansion carbon from waste ion exchange resin comprises a process of preparing expansion carbon by impregnating the waste ion exchange resin with a 0.5M KOH or K2CO3 solution, thereby stabilizing the waste ion exchange resin and heat treating the impregnated waste ion exchange resin after removing inorganic matter adsorbed onto the waste ion exchange resin using a 1N hydrochloric acid solution, wherein the expanded carbon preparation process comprises a step of removing the inorganic matter adsorbed onto the waste ion exchange resin by dipping the waste ion exchange resin into the hydrochloric acid solution at an ordinary temperature for 24 hours in a ratio of 200 cc of the 1N hydrochloric acid solution to 10 g of the waste ion exchange resin; a step of stabilizing the inorganic matter removed waste ion exchange resin in air at a temperature of 250 deg.C for 4 hours; and a step of maintaining the heated waste ion exchange resin for 30 minutes by heating the impregnated waste ion exchange resin to a temperature of 700 deg.C in a high temperature increasing rate after impregnating the waste ion exchange resin with the potassium hydroxide or potassium carbonate solution for 4 hours in a ratio of 200 cc of 0.5M potassium hydroxide or potassium carbonate solution to 10 g of the stabilized waste ion exchange resin.
机译:用途:由废离子交换树脂制备膨胀碳的方法,其中所述废离子交换树脂被循环利用,并且通过在使用后废弃的废离子交换树脂中制备膨胀碳来制备不含石墨和硫酸的膨胀碳。去除水中所含的无机物。组成:由废离子交换树脂制备膨胀碳的方法包括以下步骤:通过用0.5M KOH或K2CO3溶液浸渍废离子交换树脂来制备膨胀碳,从而稳定废离子交换树脂并对其进行浸渍处理在使用1N盐酸溶液除去吸附在废离子交换树脂上的无机物后的交换树脂,其中膨胀碳制备工艺包括以下步骤:通过将废离子交换树脂浸入废离子交换树脂中,除去吸附在废离子交换树脂上的无机物。在常温下的盐酸溶液中,以200 cc的1N盐酸溶液与10 g的废离子交换树脂的比例,进行24小时的处理;在250℃的空气中使除去了无机物的废离子交换树脂稳定4小时的步骤;以及在通过用氢氧化钾或碳酸钾浸渍废离子交换树脂之后以高温升高速率将浸渍的废离子交换树脂加热到700℃的温度来保持加热的废离子交换树脂30分钟的步骤。以200毫升0.5M氢氧化钾或碳酸钾溶液与10克稳定化的废离子交换树脂的比例,将溶液溶解4小时。

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