首页> 外国专利> PROCESS FOR PREPARING BIODEGRADABLE POLYESTER COPOLYMER WITH IMPROVED CUTTING PROPERTY AND MECHANICAL STRENGTH BY EMPLOYING POLYLACTIC ACID

PROCESS FOR PREPARING BIODEGRADABLE POLYESTER COPOLYMER WITH IMPROVED CUTTING PROPERTY AND MECHANICAL STRENGTH BY EMPLOYING POLYLACTIC ACID

机译:通过聚乳酸制备具有改进的切割性能和机械强度的可生物降解聚酯共聚物的工艺。

摘要

PURPOSE: A process for preparing a biodegradable polyester copolymer with improved cutting property is provided to enhance the productivity and to prevent the decrease of physical properties caused by the delayed cutting. CONSTITUTION: The process for preparing a biodegradable polyester copolymer, namely a 3-components copolymer of polylactic acid(PLA)/aromatic/aliphatic polyester comprises copolymerizing 20-80 parts by weight of an aromatic-aliphatic polyester oligomer with 80-20 parts by weight of polylactic acid resin by melt-mixing. In the process, the aromatic-aliphatic polyester oligomer has a polymerization degree of 10 or less, in which the aromatic component is contained in the range of 10-40 mol% and is at least one selected from a dicarboxylic acid of ROOC-Ar-COOR', or a derivative thereof, and the aliphatic component is at least one selected from a dicarboxylic acid of ROOC(CH2)nCOOR' or a derivative thereof. The polylactic acid comprises L-, D- or L,D-lactic acid having a molecular weight of 10,000 or more.
机译:目的:提供一种制备具有改善的切割性能的可生物降解的聚酯共聚物的方法,以提高生产率并防止由于延迟切割而导致的物理性能下降。组成:一种可生物降解的聚酯共聚物,即聚乳酸(PLA)/芳族/脂肪族聚酯的三组分共聚物的制备方法,包括将20-80重量份的芳香族-脂肪族聚酯低聚物与80-20重量份的共聚物共聚通过熔融混合制备聚乳酸树脂。在该方法中,芳族脂肪族聚酯低聚物的聚合度为10以下,其中芳族成分的含量为10-40mol%,并且是选自ROOC-Ar-的二元羧酸中的至少一种。 COOR′或其衍生物,和脂族组分是选自ROOC(CH 2)n COOR′的二元羧酸或其衍生物中的至少一种。聚乳酸包括分子量为10,000以上的L-,D-或L,D-乳酸。

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