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PROCESS FOR PREPARING BIODEGRADABLE POLYESTER COPOLYMER WITH IMPROVED CUTTING PROPERTY AND MECHANICAL STRENGTH BY EMPLOYING POLYLACTIC ACID
PROCESS FOR PREPARING BIODEGRADABLE POLYESTER COPOLYMER WITH IMPROVED CUTTING PROPERTY AND MECHANICAL STRENGTH BY EMPLOYING POLYLACTIC ACID
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机译:通过聚乳酸制备具有改进的切割性能和机械强度的可生物降解聚酯共聚物的工艺。
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摘要
PURPOSE: A process for preparing a biodegradable polyester copolymer with improved cutting property is provided to enhance the productivity and to prevent the decrease of physical properties caused by the delayed cutting. CONSTITUTION: The process for preparing a biodegradable polyester copolymer, namely a 3-components copolymer of polylactic acid(PLA)/aromatic/aliphatic polyester comprises copolymerizing 20-80 parts by weight of an aromatic-aliphatic polyester oligomer with 80-20 parts by weight of polylactic acid resin by melt-mixing. In the process, the aromatic-aliphatic polyester oligomer has a polymerization degree of 10 or less, in which the aromatic component is contained in the range of 10-40 mol% and is at least one selected from a dicarboxylic acid of ROOC-Ar-COOR', or a derivative thereof, and the aliphatic component is at least one selected from a dicarboxylic acid of ROOC(CH2)nCOOR' or a derivative thereof. The polylactic acid comprises L-, D- or L,D-lactic acid having a molecular weight of 10,000 or more.
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