首页> 外国专利> ADDITIVE COMPRISING CELLULOSE DERIVATIVES HAVING GEL-LIKE FLOWABILITY USEFUL IN COMPRESSION MOLDING OF BUILDING MATERIAL TO PROVIDE WATER RETENTION ABILITY AT HIGH TEMPERATURE, AND TO IMPROVE SURFACE QUALITY AND SHAPE STABILITY OF COMPRESSED PRODUCT

ADDITIVE COMPRISING CELLULOSE DERIVATIVES HAVING GEL-LIKE FLOWABILITY USEFUL IN COMPRESSION MOLDING OF BUILDING MATERIAL TO PROVIDE WATER RETENTION ABILITY AT HIGH TEMPERATURE, AND TO IMPROVE SURFACE QUALITY AND SHAPE STABILITY OF COMPRESSED PRODUCT

机译:包含纤维素衍生物的添加剂具有类似于凝胶的流动性,可用于建筑材料的压制成型,以提供高温下的保水能力,并改善压缩产品的表面质量和形状稳定性

摘要

PURPOSE: An additive comprising cellulose derivatives having gel-like flowability which can be suitably used in compression molding of a building material such as cement, is provided to give good water retention ability at high temperature, to reduce the pressure during compression molding, to improve discharge velocity at a discharging hole, surface quality and shape stability of the compressed product. CONSTITUTION: The additive suitably used in compression molding of a building material comprises irreversibly crosslinked cellulose ether which has gel-like flowability. The additive is produced by: carrying out alkalization of cellulose with an aqueous solution of alkali metal hydroxides in the presence of a suspending medium; reacting the alkalized cellulose with at least one alkylene oxides; reacting the alkalized cellulose with alkyl halides present in a suspending medium; subsequently or at the same time, reacting the alkalized cellulose with 0.0001-0.05 equivalent weight of a crosslinking agent; and optionally adding alkali metal hydroxides and/or an alkylating agent thereto, separating the resulted irreversibly crosslinked cellulose derivatives out of the reaction mixture, and optionally purifying and drying the resulted cellulose derivatives.
机译:用途:提供一种添加剂,其包含具有凝胶状流动性的纤维素衍生物,可适用于水泥等建筑材料的压缩成型,以在高温下提供良好的保水能力,以降低压缩成型期间的压力,从而改善排出孔处的排出速度,压缩产品的表面质量和形状稳定性。组成:适用于建筑材料压缩成型的添加剂包括不可逆交联的纤维素醚,具有凝胶状的流动性。该添加剂的生产方法是:在悬浮介质的存在下,用碱金属氢氧化物的水溶液对纤维素进行碱化;使碱化纤维素与至少一种环氧烷反应;使碱化纤维素与悬浮介质中存在的烷基卤反应;随后或同时,使碱化纤维素与0.0001-0.05当量的交联剂反应;向反应混合物中分离得到的不可逆交联的纤维素衍生物,并任选地纯化和干燥所得的纤维素衍生物,并任选地向其中添加碱金属氢氧化物和/或烷基化剂。

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