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Process for Producing Compact or Cellular Polyurethane Elastomers Based on 3,3'-Dimethyl Biphenyl 4,4'-Diisocyanate-Containing Polyisocyanate Mixtures and Isocyanate Prepolymers Suitable therefor

机译:基于包含3,3'-二甲基联苯4,4'-二异氰酸酯的多异氰酸酯混合物和适用于其的异氰酸酯预聚物生产致密或多孔聚氨酯弹性体的方法

摘要

Compact and preferably cellular polyurethane elastomers based on polyisocyanate mixtures containing 3,3'-dimethylbiphenyl 4,4'-diisocyanate are produced by reactinga) relatively high molecular weight polyhydroxyl compounds and, if desired,b) low molecular weight hydroxyl-containing chain extenders and/or crosslinkers withc) 3,3'-dimethylbiphenyl 4,4'-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or at least one aliphatic diisocyanate having from 4 to 12 carbon atoms and/or at least one cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are advantageously reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives.Isocyanate prepolymers suitable for this purpose are preferably ones based on diphenylmethane 4,4'-diisocyanate and 3,3'-dimethylbiphenyl 4,4'-diisocyanate.
机译:通过使a)较高分子量的多羟基化合物与(b)低分子量的含羟基的扩链剂和(a)反应,制得基于含有3,3'-二甲基联苯4,4'-二异氰酸酯的多异氰酸酯混合物的致密且优选为多孔聚氨酯弹性体。和/或具有c)3,3'-二甲基联苯4,4'-二异氰酸酯和至少一种选自甲苯二异氰酸酯,二苯基甲烷二异氰酸酯,1,2-二苯基乙烷二异氰酸酯和亚苯基二异氰酸酯的另外的芳族二异氰酸酯,和/或至少一种具有4至12个碳原子的脂族二异氰酸酯和/或至少一种具有6至18个碳原子的脂环族二异氰酸酯,其中形成性组分(a),(c)和(如果使用的话)(b)有利地通过以下反应进行反应:在存在或不存在d)催化剂,e)发泡剂和f)添加剂的情况下,适用于该预聚物的方法。适用于此目的的异氰酸酯预聚物优选为基于二苯甲酸酯的预聚物烷4,4'-二异氰酸酯和3,3'-二甲基联苯4,4'-二异氰酸酯。

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