PURPOSE: Provided is an organic alkali earth metal complex with thermal stability and good vaporization for formation of metal oxide composite films. The resultant complex is adapted to the production of semiconductors, photoelectrics and piezoelectrics. CONSTITUTION: The complex of organic alkali earth metals, L-M-L', is prepared by adding alcohol to organic solution containing alkali earth metal, expressed by the formula MX + xs HOR --£M(OR)2|n, followed by mixing with chelate ligands L and L', expressed by the formula £M(OR)2|n + L + L' --L-M-L', where M is Ba, Sr or Ca, L is R(CH3)CH(OH) (CH2)nCH(OH)(CH3)R'(R and R' are C1-C10 alkyl group, and n is an integer of 1-5), L' is N(CH2CH2XCH2CH2YZ)3(X and Y are O or NH, and Z is C1-C10 alkyl group).
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机译:目的:提供一种具有热稳定性和良好的汽化性的有机碱土金属配合物,用于形成金属氧化物复合膜。生成的配合物适用于半导体,光电和压电材料的生产。组成:有机碱土金属配合物LM-L'的制备方法是,将酒精加到含碱土金属的有机溶液中,用式MX + xs HOR->£M(OR)2 | n表示,然后与螯合配体L和L'混合,用式£M(OR)2 | n + L + L'-> LM-L'表示,其中M为Ba,Sr或Ca,L为R(CH3)CH (OH)(CH2)nCH(OH)(CH3)R'(R和R'为C1-C10烷基,n为1-5的整数),L'为N(CH2CH2XCH2CH2YZ)3(X和Y是O或NH,Z是C1-C10烷基)。
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