首页> 外国专利> Novel (poly)oxyalkylene block silyl ester copolymer, antifouling coating composition, antifouling coating formed from antifouling coating composition, antifouling method using antifouling coating composition and hull or underwater structure covered with antifouling coating

Novel (poly)oxyalkylene block silyl ester copolymer, antifouling coating composition, antifouling coating formed from antifouling coating composition, antifouling method using antifouling coating composition and hull or underwater structure covered with antifouling coating

机译:新型(聚)氧化烯嵌段甲硅烷基酯共聚物,防污涂料组合物,由该防污涂料组合物形成的防污涂料,使用该防污涂料组合物的防污方法以及覆盖有防污涂料的船体或水下结构

摘要

Comprising a silyl ester copolymer block units (A) and block units (B), the silyl ester copolymer block units (A) is (a) a polymerizable unsaturated carboxylic acid silyl component unit, and (b) derived from an ester the constituent unit (a) polymerization of a non-enabled and an unsaturated monomer unit, the block units (B), the following formula (1) or (2) (poly) oxyalkylene block derived from a mercapto compound represented by the silyl ester copolymer, and (poly) oxyalkylene the antifouling paint is provided which includes a block silyl ester copolymer:; or; Wherein, R 1 is one or more hydrocarbon groups or ether having from 1 to 30 carbon atoms-containing hydrocarbon group denotes a - bond; R 2 having from 1 to 30 carbon atom divalent hydrocarbon group or a group represented by the formula -CH (R 3) - [R 3 denotes a group of the formula R 4 -OR 5, R 4 is having from 1 to 30 carbon atoms 2 represents a hydrocarbon group, and R 5 are 1 represents the group of represents a hydrocarbon group - having 1 to 30 carbon atoms; X is or It represents; n is an integer from 1 to 5; m is an integer from 1 to 100; l is an integer from 1 to 5; k is an integer from 0 to 100; a is an integer of 0 or 1; j is an integer from 1 to 50; In addition, i is the valence of R 1 ordination.; If according to the invention, is reduced cracking property, the peeling resistance is reduced by the superior adhesion also to be able to adjust as required the rate of hydrolysis, antifouling performance (antifouling activity), antifouling properties (in particular, contaminated this material can form an excellent antifouling coating film from the antifouling properties) and long-term antifouling properties in many environments.
机译:由甲硅烷基酯共聚物嵌段单元(A)和嵌段单元(B)组成,甲硅烷基酯共聚物嵌段单元(A)是(a)可聚合的不饱和羧酸甲硅烷基组分单元,和(b)由酯衍生的构成单元(a)由甲硅烷基酯共聚物所代表的巯基化合物衍生的非活化和不饱和单体单元,嵌段单元(B),下式(1)或(2)的聚合(聚)氧化烯嵌段的聚合,以及提供(聚)氧化烯的防污涂料,其包括嵌段甲硅烷基酯共聚物:要么;其中,R 1 为一个或多个烃基或具有1至30个碳原子的烃基的醚表示-键;具有1至30个碳原子的二价烃基或由式 -CH(R 3)-[R 3表示的基团的R 2 表示式R的基团 4 -OR 5, R 4 具有1至30个碳原子2表示烃基,R 5 是1表示的基团表示具有1至30个碳原子的烃基; X是或它表示; n为1至5的整数; m为1〜100的整数。 l为1到5的整数; k是0至100的整数; a是0或1的整数; j为1至50的整数;另外,i是R 1 序数的化合价。如果根据本发明,降低的龟裂性,则由于优异的粘附力而降低了耐剥离性,并且还能够根据需要调节水解速度,防污性能(防污活性),防污性能(特别是污染了该材料的罐头)。通过防污性能和在许多环境下的长期防污性能可形成极好的防污涂膜。

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