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Method for Highly Efficient Hydro Carboxylation Addition of Carbon-Carbon Double Bond on the Solid-Phase
Method for Highly Efficient Hydro Carboxylation Addition of Carbon-Carbon Double Bond on the Solid-Phase
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机译:固相上碳-碳双键高效加氢羧化的方法
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摘要
The present invention solid carbon attached to the support-related to a high efficiency hydro-carboxylate additional method of the carbon-carbon double bond compounds, more specifically, meta-chloroperbenzoic acid the organic oxidizing agent under the presence of carbon attached to the solid support of (m -cpba) - carbon double bond compound in the hydrocarbyl, in performing the reaction of adding the carboxylate, the specific solvent system and an organic oxidizing agent, and carboxylate by putting the precursor in a reaction vessel one performs the vessel reaction (one-pot reaction) of interest It relates to a high efficiency hydro-carboxylate additional method of the carbon-carbon double bond compound-dihydro-carboxylate adduct effectively the carbon attached to the solid support to be obtained.; The process according to the invention are useful in a variety of molecular composite useful for the lead compound search using combinatorial chemical synthesis technology to the introduction of various functional groups, such as if the group is hydroxy to a carbon that various carboxyl group introduced can be adjacent ester, ether in the molecule.
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