MIXTURE activated starter, methods of obtaining such a mixture, batch or semi-batch process addition polymerization of alkylene oxides in an activated starter mixture and obtain the above method is simple polyols, polyester polyols and polyols Copolymer ethers and esters

摘要

1. the mixture with activated initiator, u0432u043au043bu044eu0447u0430u044eu0449u0430u00a0:;(a) at least one pre activated initiator, u0441u043eu0441u0442u043eu00a0u0449u0438u0439 of:;(i) at least one of the first pioneers of equivalent mass of at least 70;;(ii) at least one vapors; and;(iii) at least one u0434u043cu0446 - catalyst; and;(b) at least 2 mol.%, at least one of the two initiators of equivalent mass, equivalent mass u043au043eu0442u043eu0440u0430u00a0 less the first initiator.;2. mix 1, in which the first initiator is equivalent to mass, greater or equal to approximately 200.;3. mix 1, in which the second initiator is the equivalent of less than or equal to about 80.;4. mix 1, in which the first initiator u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043fu043eu043bu0438u043eu043au0441u0438u043fu0440u043eu043fu0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u044du0442u0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, simple u043fu043eu043bu0438u0442u0435u0442u0440u0430u043cu0435u0442u0438u043bu0435u043du043eu0432u044bu043c ether u0433u043bu0438u043au043eu043bu00a0, u043fu0440u043eu043fu043eu043au0441u0438u043bu0438u0440u043eu0432u0430 u043du043du044bu043c glycerin, u0442u0440u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0430u043bu043au043eu043au0441u0438u043bu0438u0440u043eu0432u0430u043du043du044bu043c u0430u043bu043bu0438u043bu043eu0432u044bu043c alcohol or their mixture.;5. mix 1, in which the second initiator u00a0u0432u043bu00a0u0435u0442u0441u00a0 water u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0434u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0442u0440u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u043du0435u043eu043fu0435u043du0442u0438u043bu0433u043bu0438u043au043eu043bu0435u043c, u0434u0438u044du0442u0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0442u0440u0438u044du0442u0438u043bu0435 u043du0433u043bu0438u043au043eu043bu0435u043c, glycerin, u0442u0440u0438u043cu0435u0442u0438u043bu043eu043bu043fu0440u043eu043fu0430u043du043eu043c, u0441u043eu0440u0431u0438u0442u043eu043c, methanol, ethanol, u0431u0443u0442u0430u043du043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u043fu0440u043eu043fu0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u044du0442u0438u043bu0435u043d - u043fu043eu043bu0438u043eu043bu043eu043c, u0430u043bu043au043eu043au0441u0438u043bu0438u0440u043eu0432u0430u043du043du044bu043c allyl u043eu0432u044bu043c alcohol or their mixture.;6. mix 1, in which the pre activated initiator is blended with at least 80 mol.% of the second initiator.;7. mix 1, in which the catalyst on the basis of u0434u0432u0443u043cu0435u0442u0430u043bu043bu0438u0447u0435u0441u043au043eu0433u043e cyanide u00a0u0432u043bu00a0u0435u0442u0441u00a0 u0446u0438u043du043au0433u0435u043au0441u0430u0446u0438u0430u043du043au043eu0431u0430u043bu044cu0442u0430u0442.;8. method u043fu043eu043bu0443u0447u0435u043du0438u00a0 mixture with activated initiator, comprising of:;(a) at least one pre activated initiator, u0441u043eu0441u0442u043eu00a0u0449u0435u0433u043e of:;(i) at least one of the first pioneers of equivalent mass, u0441u043eu0441u0442u0430u0432u043bu00a0u044eu0449u0435u0439 at least 70;;(ii) at least one vapors; and;(iii) at least one u0434u043cu0446 - catalyst;;(b) at least 2 mol.%, at least one of the two initiators with equivalent mass, the mass of the first u043au043eu0442u043eu0440u0430u00a0 less than u044du043au0432u0438u0432u0430u043bu0435u043du0442u043du0430u00a0 initiator.;9. method for point 9, in which the first initiator is equivalent to mass, greater or equal to approximately 200.;10. method for point 9, which the second initiator is the equivalent of less than or equal to about 80.;11. method for point 9, in which the first initiator u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043fu043eu043bu0438u043eu043au0441u0438u043fu0440u043eu043fu0438u043bu0435u043d - u043fu043eu043bu0438u043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u044du0442u0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, simple u043fu043eu043bu0438u0442u0435u0442u0440u0430u043cu0435u0442u0438u043bu0435u043du043eu0432u044bu043c ether u0433u043bu0438u043au043eu043bu00a0, u043fu0440u043eu043fu043eu043au0441u0438u043bu0438u0440u043eu0432 u0430u043du043du044bu043c glycerin, u0442u0440u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0430u043bu043au043eu043au0441u0438u043bu0438u0440u043eu0432u0430u043du043du044bu043c u0430u043bu043bu0438u043bu043eu0432u044bu043c alcohol or their mixture.;12. method for point 9, in which the second initiator u00a0u0432u043bu00a0u0435u0442u0441u00a0 water u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0434u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0442u0440u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u043du0435u043eu043fu0435u043du0442u0438u043bu0433u043bu0438u043au043eu043bu0435u043c, u0434u0438u044du0442u0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0442u0440u0438u044du0442u0438u043b u0435u043du0433u043bu0438u043au043eu043bu0435u043c, glycerin, u0442u0440u0438u043cu0435u0442u0438u043bu043eu043bu043fu0440u043eu043fu0430u043du043eu043c, u0441u043eu0440u0431u0438u0442u043eu043c, methanol, ethanol, u0431u0443u0442u0430u043du043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u043fu0440u043eu043fu0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u044du0442u0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, u0430u043bu043au043eu043au0441u0438u043bu0438u0440u043eu0432u0430u043du043du044bu043c allyl u043eu0432u044bu043c alcohol or their mixture.;13. method for point 9, in which pre activated initiator u0441u043cu0435u0448u0438u0432u0430u0435u0442u0441u00a0 with at least 80 mol.% of the second initiator.;14. method for point 9, in which the catalyst on the basis of u0434u0432u0443u043cu0435u0442u0430u043bu043bu0438u0447u0435u0441u043au043eu0433u043e cyanide u00a0u0432u043bu00a0u0435u0442u0441u00a0 u0446u0438u043du043au0433u0435u043au0441u0430u0446u0438u0430u043du043au043eu0431u0430u043bu044cu0442u0430u0442.;15. periodic or u043fu043eu043bu0443u043fu0435u0440u0438u043eu0434u0438u0447u0435u0441u043au0438u0439 way u0430u0434u0434u0438u0442u0438u0432u043du043eu0439 polymerization u0430u043bu043au0438u043bu0435u043du043eu043au0441u0438u0434u0430 in mixture with activated initiator comprising interaction:;(1) at least one mixture with activated initiator comprising a mixture of:;(a) at least one pre activated initiator, u0441u043eu0441u0442u043eu00a0u0449u0435u0433u043e of:;(i) at least one of the first pioneers of equivalent mass, u0441u043eu0441u0442u0430u0432u043bu00a0u044eu0449u0435u0439 at least 70;;(and) the at least one vapors; and;(iii) at least one u0434u043cu0446 - catalyst;;and;(b) at least 2 mol.%, at least one of the two initiators with equivalent mass, the mass of less than u044du043au0432u0438u0432u0430u043bu0435u043du0442u043du0430u00a0 first initiator;;with;(2) at least one hchs.;16. method for p.15, in which the first initiator is equivalent to mass, greater or equal to approximately 200.;17. method for p.15, which second initiator is the equivalent of less than or equal to about 80.;18. method for p.15, in which the first initiator u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043fu043eu043bu0438u043eu043au0441u0438u043fu0440u043eu043fu0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, u043fu043eu043bu0438u043eu043au0441u0438u044du0442u0438u043bu0435u043du043fu043eu043bu0438u043eu043bu043eu043c, simple u043fu043eu043bu0438u0442u0435u0442u0440u0430u043cu0435u0442u0438u043bu0435u043du043eu0432u044bu043c ether u0433u043bu0438u043au043eu043bu00a0, u043fu0440u043eu043fu043eu043au0441u0438u043bu0438u0440u043eu0432 u0430u043du043du044bu043c glycerin, u0442u0440u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu0435u043c, u0430u043bu043au043eu043au0441u0438u043bu0438u0440u043eu0432u0430u043du043du044bu043c u0430u043bu043bu0438u043bu043eu0432u044bu043c alcohol or their mixture.;19. the way in which the second u00a0u0432u043bu00a0u0435u0442u0441u00a0 p.15, initiator, water, propylene glycol, dipropylene glycol, u0442u0440u0438u043fu0440u043eu043fu0438u043bu0435u043du0433u043bu0438u043au043eu043bu044c, u043du0435u043eu043fu0435u043du0442u0438u043bu0433u043bu0438u043au043eu043bu044c, diethylene glycol, u0442u0440u0438u044du0442u0438u043bu0435u043du0433 u043bu0438u043au043eu043bu044c u0442u0440u0438u043cu0435u0442u0438u043bu043eu043bu043fu0440u043eu043fu0430u043d, sorbitol, glycerol, methanol, ethanol, u0431u0443u0442u0430u043du043eu043b, u043fu043eu043bu0438u043eu043au0441u0438u043fu0440u043eu043fu0438u043bu0435u043du043fu043eu043bu0438u043eu043b, u043fu043eu043bu0438u043eu043au0441u0438u044du0442u0438u043bu0435u043du043fu043eu043bu0438u043eu043b, u0430u043bu043au043eu043au0441u0438u043bu0438u0440u043eu0432u0430u043du043du044bu0439 allyl alcohol or their u0441u043cu0435u0441 b,;20. method for p.15, in which pre activated initiator are mixed with at least 80 mol.% of the second initiator.;21. method for p.15, in which the catalyst on the basis of u0434u0432u0443u043cu0435u0442u0430u043bu043bu0438u0447u0435u0441u043au043eu0433u043e cyanide u00a0u0432u043bu00a0u0435u0442u0441u00a0 u0446u0438u043du043au0433u0435u043au0441u0430u0446u0438u0430u043du043au043eu0431u0430u043bu044cu0442u0430u0442.;22. a simple method for the u043fu043eu043bu0438u044du0444u0438u0440u043fu043eu043bu0438u043eu043b, p.15.;23. a method for the u043fu043eu043bu0438u044du0444u0438u0440u043fu043eu043bu0438u043eu043b, p.15.;24. u043fu043eu043bu0438u043eu043b simple ether copolymer and the method for complex air, p.15.