Bismuth and phosphorus-containing catalyst support, reforming catalysts based on them, PREPARATION AND METHOD FOR REFORMING PETROLEUM

摘要

1. a u0434u043bu00a0 catalyst containing particles of u0430u043bu044eu043cu0438u043du0438u00a0, which essentially uniformly distributed bismuth and phosphorous in catalytically effective u043au043eu043du0446u0435u043du0442 u0440u0430u0446u0438u00a0u0445.;2. a u0434u043bu00a0 catalyst for 1, in which u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 bismuth u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range of from 0.05 to 0.1 mas.%, and the u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 phosphorus u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range of from 0.05 to 0.6 mas.%.;3. a u0434u043bu00a0 catalyst for 1, in which u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 bismuth u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range of from 0.05 to 0.1 mas.%, and the u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 phosphorus u043du0430u0445u043eu0434u0438u0442u0441u00a0 interval from 0.1 to 0.4 mas.%.;4. a u0434u043bu00a0 catalyst for 1, in which u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 bismuth u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range of from 0.05 to 0.1 mas.%, and the u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 phosphorus u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.25 and 0.35 mas. %.;5. a u0434u043bu00a0 catalyst for 1, in which the particles are received applications.;6. method u0438u0437u0433u043eu0442u043eu0432u043bu0435u043du0438u00a0 u043du043eu0441u0438u0442u0435u043bu00a0 u0434u043bu00a0 catalyst comprising;(a) preparation of the solution containing the predecessor of bismuth, and the solution containing the predecessor of phosphorus;;(b) preparation of mixture of u0430u043bu044eu043cu0438u043du0438u00a0 and u0437u043eu043bu00a0 u0430u043bu044eu043cu0438u043du0438u00a0 oxide;;(c) mixing a mixture obtained in the stage (b), with solutions, cooked on the stage (a), a predecessor u043du043eu0441u0438u0442u0435u043bu00a0 containing substantially uniformly races u043fu0440u0435u0434u0435u043bu0435u043du043du044bu0435 phosphorus and bismuth;;(d) molding the particles u043du043eu0441u0438u0442u0435u043bu00a0 predecessor; and;(e) drying and u043fu0440u043eu043au0430u043bu0438u0432u0430u043du0438u0435 particles.;7. method for p.6, which predecessor bismuth select from group u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of bi (no3) 35u043d2u043e, BiCl3, BiOCl, BiBr3, acetate bi, bi and bi u0430u043bu043au043eu0433u043eu043bu00a0u0442u043eu0432 synthase.;8. method for p.6, which a predecessor of bismuth u00a0u0432u043bu00a0u0435u0442u0441u00a0 bi (no3) 35u043d2O.;9. method for p.6, which predecessor phosphorus select from group u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of u043d3PO4, u043d3u0440u043e3, u043d3u0440u043e2, NH4H2PO4 and (nh4) 2HPO4.;10. method for p.6, in which the phosphorus u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043d3PO4.;11. method for p.6, which mixture is u0430u043bu044eu043cu0438u043du0438u00a0 oxide and oxide u0437u043eu043bu00a0 u0430u043bu044eu043cu0438u043du0438u00a0 contains 62 masses.% oxide u0430u043bu044eu043cu0438u043du0438u00a0 and the rest of u0430u043bu044eu043cu0438u043du0438u00a0 sool, switzerland.;12. a u0434u043bu00a0 catalyst, the way for p.6.;13. the reformer catalyst oil containing a u0434u043bu00a0 catalyst for catalytically effective amount of platinum and 1 and chlorine.;14. catalyst on p.13, further containing catalytically effective amounts of u0440u0435u043du0438u00a0.;15. catalyst on p.13, in which the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.1 and 1 mas.% of the mass of catalyst and the amount of chlorine in the range of from 0.05 to 2 u043du0430u0445u043eu0434u0438u0442u0441u00a0 mas. from the mass of the catalyst.;16. catalyst on p.13, in which the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range from 0.15 to 0.6 mas.% of the mass of catalyst and the amount of chlorine u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.8 to 1.2 mas .% of the mass of the catalyst.;17. catalyst on p.13, in which the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.2 to 0.3 mas.% of the mass of catalyst and the amount of chlorine in the range of 0.9 to 1.1 u043du0430u0445u043eu0434u0438u0442u0441u00a0 mas. percent of the mass of the catalyst.;18. catalyst on p.13, in which the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.1 and 1 mas.% of the mass of catalyst and the amount of chlorine in the range of from 0.05 to 2 u043du0430u0445u043eu0434u0438u0442u0441u00a0 mas. from the mass of catalyst, where the catalyst further contains from 0.01 to 1 mas. u0440u0435u043du0438u00a0.;19. catalyst on p.13, in which the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range from 0.15 to 0.6 mas.% of the mass of catalyst and the amount of chlorine u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.8 to 1.2 mas .% of the mass of catalyst, where the catalyst further contains from 0.1 to 0.5 mas. u0440u0435u043du0438u00a0.;20. catalyst on p.13, in which the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.2 to 0.3 mas.% of the mass of catalyst and the amount of chlorine in the range of 0.9 to 1.1 u043du0430u0445u043eu0434u0438u0442u0441u00a0 mas. % of the mass of catalyst, where the catalyst further contains from 0.2 to 0.45 mas. u0440u0435u043du0438u00a0.;21. catalyst on p.13, which u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 bismuth in the form u0434u043bu00a0 catalyst u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range of from 0.05 to 0.1 mas.% of the mass of catalyst and u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 phosphorus in the medium u0434u043bu00a0 catalyst u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.25 and 0.35 mas.%; and the amount of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.2 to 0.3 mas.% of the mass of catalyst and the amount of u0445u043b ora u043du0430u0445u043eu0434u0438u0442u0441u00a0 interval of 0.9 to 1.1 mas.percent of the mass of the catalyst.;22. catalyst on p.13, which u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 bismuth in the form u0434u043bu00a0 catalyst u043du0430u0445u043eu0434u0438u0442u0441u00a0 in the range of from 0.05 to 0.1 mas.% of the mass of catalyst and u043au043eu043du0446u0435u043du0442u0440u0430u0446u0438u00a0 phosphorus in the medium u0434u043bu00a0 catalyst u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.25 and 0.35 mas.%; the number of platinum u043du0430u0445u043eu0434u0438u0442u0441u00a0 between 0.2 to 0.3 mas.% of the mass of catalyst, and amount of chlo ra u043du0430u0445u043eu0434u0438u0442u0441u00a0 interval of 0.9 to 1.1 mas.percent of the mass of the catalyst; and the catalyst further contains from 0.2 to 0.45 mas. u0440u0435u043du0438u00a0.;23. a catalyst prepared by means of an u043fu0440u043eu043fu0438u0442u043au0443 u043du043eu0441u0438u0442u0435u043bu00a0 u0434u043bu00a0 catalyst on p.12 with catalytically effective quantities of platinum and chlorine.;24. the catalyst for the p.23, containing a u0434u043bu00a0 imbued with a catalytically effective amount of a catalyst, u0440u0435u043du0438u00a0.;25. a reformer after hydro oil comprising u043au043eu043du0442u0430u043au0442u0438u0440u043eu0432u0430u043du0438u0435 oil with the catalyst in the presence of hydrogen on p.13 at elevated temperature and pressure.