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Membranes for the dehydration of liquid and vapor organics / water - mixtures with layers having release activity on the basis of polyacrylamide

机译:用于液体和蒸气有机物/水脱水的膜-具有在聚丙烯酰胺基础上具有释放活性的层的混合物

摘要

Membrane with a dense, non-porous separating layer of one or more layers of a polymer in the form of a homopolymer, copolymer, graft homo polymer and / or graft copolymer, which, by means of a diacylkupplung of acid amides having carboxylic acid groups with elimination of water is crosslinked, obtainable bya) of a base polymer having an acidamide group is assumed,b) the base polymer in an aqueous or aqueous / organic solvent is at least partially dissolved,c) the base polymer by partial hydrolysis of its acid amides is modified, wherein the for crosslinking by means of diacylkupplung required carboxylic acid groups are formed, and at the same time with the elimination of water draining crosslinking of the carboxylic acid groups is carried out with the acid amides.
机译:具有一层或多层聚合物的致密,无孔分隔层的膜,所述聚合物为均聚物,共聚物,接枝均聚物和/或接枝共聚物的形式,其通过具有羧酸基团的酰胺的二酰氯连接在消除水的情况下是可交联的,可以通过以下方式获得:a)假定具有酰胺基的基础聚合物; b)在水性或水/有机溶剂中的基础聚合物至少部分溶解; c)通过部分水解其基础聚合物酰胺被改性,其中形成用于通过双酰基交联所需的羧酸基团进行交联的方法,并且在消除排水的同时,与酰胺基进行羧酸基团的交联。

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