Composition for controlling animal pests comprises a synergistic combination of a nicotinergic acetylcholine receptor agonist or antagonist and an anthranilamide derivative

摘要

Composition comprising a synergistic combination of a nicotinergic acetylcholine receptor agonist or antagonist (I) and an anthranilamide derivative (II) is new. Composition comprising a synergistic combination of a nicotinergic acetylcholine receptor agonist or antagonist of formula (I) and an anthranilamide derivative of formula (II) is new. [Image] R : H or optionally substituted acyl, alkyl, aryl, aralkyl, heterocyclyl, heteroaryl or heteroarylalkyl; A : H, acyl, alkyl or aryl or a bifunctional group bonded to Z; E : an electron-withdrawing group; X : CH or N, or C bonded to Z; Z : alkyl, OR, SR or N(R) 2, or a bifunctional group bonded to A or X; A 1, A 2O or S; X 1N or CR 1 0; R 1H or optionally substituted C1-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkynyl or C3-C6-Cycloalkyl; R 2H, C1-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkynyl, C3-C6-Cycloalkyl, C1C4-Alkoxy, C1-C4-Alkylamino, C2-C8-Dialkylamino, C3-C6-Cycloalkylamino, C2-C6 Alkoxycarbonyl or C1-C6-Alkylcarbonyl; R 3H, R 1 1 or optionally substituted C1-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkynyl, C3-C6-Cycloalkyl; R 2+R3 : a ring M; R 4H, C1-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkynyl, C3-C6-Cycloalkyl, C1-C6 Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkynyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Nitro, Hydroxy, C1-C4-Alkoxy, C1-C4-Haloalkoxy, C1-C4-Alkylthio, C1-C4-Alkylsulfinyl, C1-C4-Alkylsulfonyl, C1-C4-Haloalkylthio, C1-C4-Haloalkylsulfinyl, C1-C4-Haloalkylsulfonyl, C1-C4-Alkylamino, C2-C8-Dialkylamino, C3-C6-Cycloalkylamino, C3-C6-Trialkylsilyl or optionally substituted Phenyl, Benzyl or Phenoxy; R 5, R 8H, Halogen or optionally substituted C1-C4-Alkyl, C1-C4-Haloalkyl, R 1 2, G, J, -OJ, -OG, -S(O) p-J, -S(O) p-G, -S(O)p-phenyl; G : a 5- or 6-membered non-aromatic carbocyclic or heterocyclic ring optionally containing 1 or 2 C(=O), SO or S(=O)Z ring members and optionally substituted; J : an optionally substituted 5- or 6-membered heteroaromatic ring; R 6-C(=E 1)R 1 9, -LC(=E 1) 1 9, C(=E 1)LR 1 9, -LC(=E 1)LR 1 9, -OP(=Q)(OR 1 9)2, -SO 2LR 1 8 or -LSO 2LR 1 9; E 1O, S, N-R 1 5, N-OR 1 5, N-N(R 1 5) 2, N-S=O, N-CN or N-NO 2; R 7H, C1-C4-Alkyl, C1-C4-Haloalkyl, Halogen, C1-C4-Alkoxy, C1-C4 Haloalkoxy, C1-C4-Alkylthio, C1-C4-Alkylsulfinyl, C1-C4-Alkylsulfonyl, C1-C4 Haloalkylthio, C1-C4-Haloalkylsulfinyl, C1-C4-Haloalkylsulfonyl; R 9C1-C4-Haloalkyl, C1-C4-Haloalkoxy, C1-C4-Haloalkylsulfinyl or Halogen; R 1 0H, C1-C4-Alkyl, C1-C4-Haloalkyl, Halogen, Cyano or C1-C4 Haloalkoxy; R 1 1optionally mono- to trisubstituted C1-C6-Alkylthio, C1-C6-Alkylsulfenyl, C1-C6-Haloalkythio, C1-C6 Haloalkylsulfenyl, Phenylthio or Phenylsulfenyl; L : O, NR 1 8 or S; R 1 2-B(OR 1 7) 2, Amino, SH, Thiocyanato, C3-C8 Trialkylsilyloxy, C1-C4-Alkyldisulfide, -SF 5, -C(=E)R 1 9, -LC(=E)R 1 9, -C(=E)LR 1 9, -LC(=E)LR 1 9, -OP(=Q)(OR 1 9) 2, -SO 2LR 1 9 or -LSO 2LR 1 9; Q : O or S; R 1 3H or optionally substituted C1-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkynyl or C3-C6 Cycloalkyl; R 1 4optionally substituted C1-C20-Alkyl, C2-C20-Alkenyl, C2-C20-Alkynyl or C3-C6-Cycloalkyl; R 1 5H or optionally substituted C1-C6-Haloalkyl or C1-C6-Alkyl, or N(R 1 5) 2 forms a ring M; R 1 6C1-C12-Alkyl or C1-C12-Haloalkyl, or N(R 1 6) 2 forms a ring M; R 1 7H or C1-C4-Alkyl, or B(OR 1 7) 2 is a ring in which both O atoms are connected with a chain of 2-3 C atoms, optionally substituted with 1 or 2 of methyl oder C2-C6 Alkoxycarbonyl; R 1 8H, C1-C6 Alkyl or C1-C6-Haloalkyl, or N(R 1 3)(R 1 8) forms a ring M; R 1 9H or optionally substituted C1-C6-Alkyl; M : an optionally substituted ring comprising an N atom, 2-6 C atoms and optionally another N, O or S atom; n : 0 or 1; p : 0, 1 or 2; when (a) R 5H, C1-C6-Alkyl, C1-C6-Haloalkyl, C2-C6 Haloalkenyl, C2-C6-Haloalkynyl, C1-C4-Haloalkoxy, C1-C4-Haloalkylthio or Halogen steht and (b) R 8 = H, C1-C6-Alkyl, C1-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6 Haloalkynyl, C1-C4-Haloalkoxy, C1-C4-Haloalkylthio, Halogen, C2-C4-Alkylcarbonyl, C2-C6 Alkoxycarbonyl, C2-C6-Alkylaminocarbonyl or C3-C8 Dialkylaminocarbonyl, (c) at least one of R 6, R 1 1 and R 1 2 is present and (d) R 1 2 is not present, then R 6 or R 1 1 is not C2-C6-Alkylcarbonyl, C2-C6 Alkoxycarbonyl, C2-C6-Alkylaminocarbonyl or C3-C8-Dialkylaminocarbonyl. Full definitions are given in the Definitions Field (Full Definitions). ACTIVITY : Insecticide; Acaricide; Nematocide. MECHANISM OF ACTION : Nicotinergic acetylcholine receptor agonist; Nicotinergic acetylcholine receptor antagonist.