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A method for the preparation of aqueous urea, melamine formaldehyde - - - aminoplast resins, their use as adhesives for the production of wood materials and resulting wood materials

机译:一种制备含水尿素,三聚氰胺甲醛---氨基塑料树脂的方法,它们用作生产木材和所得木材的粘合剂

摘要

Is prepared in such a resin with a melamine-formaldehyde resin in the final 10 - 40% by weight, by condensing urea and formaldehyde and melamine, and by addition of urea in order to obtain a final molar ratio f / nh2 of 0, 25 - 0, 85. (a) is heated at reflux, up to 15 min at ph 7 - 8, 5, a mixture in aqueous medium of urea, melamine formol and f / nh2 = 0, 85 - 1, 15; (b) the 1ère step of condensation to ph 5 - 6, 5 and 70degrec - 100degrec, until a degree of condensation, corresponding to a viscosity at 25degrec whose value depends on the active material, and it stops the condensation by bringing the ph at 7 - 8, and the temperature to 60 - 80degrec; (c) is carried out by adding 2ème step of condensation of formaldehyde, urea, melamine for an f / nh2 of 0, 6 - 0, 9, and it is condensed at ph 8 - 10 and 70 - 100 grade c, until a degree of condensation, corresponding to a viscosity at 25degrec whose value depends on the active material, and (d) is carried out, a post - addition of urea, nh2 group comprising the moles of urea and melamine.
机译:在这种树脂中与三聚氰胺-甲醛树脂制成最终重量比为10%至40%的树脂,方法是缩合尿素,甲醛和三聚氰胺,并加入尿素以获得最终摩尔比f / nh2为0、25 (a)在回流下加热,在pH 7-8、5下加热至15分钟,这是尿素,三聚氰胺甲醛的水介质中的混合物和f / nh 2 = 0、85-1、15; (b)从1ère缩合至pH 5-6、5和70degrec-100degrec的步骤,直到凝结度(对应于25degrec的粘度,其值取决于活性物质)为止,并通过将ph值降至25来停止凝结7-8,温度升至60-80degrec; (c)通过添加甲醛,尿素,三聚氰胺的2ème缩合步骤进行,f / nh2为0、6-0、9,并在8-8级和70-100级c级下冷凝,直至缩合度,对应于25℃下的粘度,其值取决于活性材料,并且(d)进行脲的后添加,nh 2基团包括脲和三聚氰胺的摩尔数。

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