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Polyorganosiloxane-containing graft copolymer, resin composition containing the same and method of manufacturing the polyorganosiloxane emulsion

机译:含聚有机硅氧烷的接枝共聚物,包含该接枝共聚物的树脂组合物以及聚有机硅氧烷乳液的制造方法

摘要

Consisting of (C) copolymerizable monomer other polyfunctional monomers containing two or more polymerizable unsaturated bond in the molecule and (B) in the presence of a polyorganosiloxane latex (A) state polyorganosiloxane-containing graft copolymer by polymerizing (D) 0 - 10 parts by weight of vinyl monomer, E is by polymerizing the vinyl monomer (E) further. It is possible to be incorporated into the thermoplastic resin as a flame retardant, to obtain a resin composition having excellent impact resistance and flame retardancy. Method for producing a polyorganosiloxane emulsion of adding partial hydrolytic condensate thereof or condensation reaction of organosilane and polyorganosiloxane obtained by emulsion polymerization under the acidic conditions of pH5 following cyclic organosiloxane. It is possible to improve the polymerization conversion rate.
机译:(C)可共聚单体由在分子中含有两个或多个可聚合不饱和键的其他多官能单体和(B)在聚有机硅氧烷胶乳的存在下(A)状态的含聚有机硅氧烷的接枝共聚物通过将(D)0-10份乙烯基单体的重量为E时,进一步使乙烯基单体(E)聚合。可以将其作为阻燃剂掺入热塑性树脂中,以获得具有优异的耐冲击性和阻燃性的树脂组合物。在环状有机硅氧烷之后,在pH5的酸性条件下,通过添加其部分水解缩合物或通过乳液聚合获得的有机硅烷与聚有机硅氧烷的缩合反应的聚有机硅氧烷乳液的制备方法。可以提高聚合转化率。

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