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Toughened nylon, the process of preparing it and its use

机译:增韧尼龙,其制备方法及其用途

摘要

A toughened nylon that comprises a matrix nylon and a long-chain nylon is described. The matrix nylon is prepared by the homopolymerization or copolymerization of cyclic lactams monomers and their corresponding amino acids. The structure of said cyclic lactams is represented by Formula (I) and the structure of amino acids is represented by (I′). In Formula (I) and (I′) A is H or alkyl with 1-8 carbon and 3≦n≦11. The long-chain nylon is selected from nylons that contain repeating units having structures represented by Formula (II), (III) or (IV). In Formula (II) D is —(CH2)x—, in which H may be substituted with C1-4 alkyl optionally; E is —(CH2)y— or phenylene, in which H may be substituted with C1-4 alkyl optionally; 4≦x≦34 and 4≦y≦34. In Formula (IV) 5≦u≦34, 5≦v≦34, and u≠v. The proportion of said long-chain nylon in the total weight of toughened nylon is 2-45%. As the toughened nylon has very good interface combination, only one melting peak is detected with differential scanning calorimetry. Besides the preparation process and application of the toughened nylon are described hereafter too. embedded image
机译:描述了一种包括基体尼龙和长链尼龙的增韧尼龙。基体尼龙是通过环状内酰胺单体及其相应氨基酸的均聚或共聚制备的。所述环状内酰胺的结构由式(I)表示,氨基酸的结构由(I')表示。在式(I)和(I')中,A是H或具有1-8个碳和3≤n≤11的烷基。长链尼龙选自包含具有式(II),(III)或(IV)表示的结构的重复单元的尼龙。式(II)中,D为-(CH 2 x -,其中H可任选被C 1-4 烷基取代; E为-(CH 2 y -或亚苯基,其中H可任选被C 1-4 烷基取代; 4≤x≤34且4≤y≤34。在式(IV)中,5≤u≤34,5≤v≤34,并且u≠v。所述长链尼龙在增韧尼龙的总重量中的比例为2-45%。由于增韧的尼龙具有非常好的界面组合,因此使用差示扫描量热法只能检测到一个熔融峰。除了增韧尼龙的制备方法和应用之外,下文也将进行描述。 “嵌入式图像”

著录项

  • 公开/公告号US2006205892A1

    专利类型

  • 公开/公告日2006-09-14

    原文格式PDF

  • 申请/专利权人 GUISHENG YANG;TINGXIU XIE;

    申请/专利号US20050553019

  • 发明设计人 TINGXIU XIE;GUISHENG YANG;

    申请日2004-04-19

  • 分类号C08G69/48;

  • 国家 US

  • 入库时间 2022-08-21 21:47:55

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