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Efficient aziridination of olefins catalyzed by dirhodium catalysts
Efficient aziridination of olefins catalyzed by dirhodium catalysts
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机译:ho催化剂催化烯烃的高效叠氮化
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摘要
This invention relates to compositions and methods for achieving the efficient aziridination of organic molecules, especially olefins. More specifically, the invention is directed to a mild, selective, and efficient aziridination protocol that involves catalysis by a mixed-valent dirhodium(II,III) catalyst (Rh25+). Especially preferred sources for forming such mixed-valent dirhodium(II,III) catalyst (Rh25+) are dirhodium(II) carboxamidates, such as dirhodium(II) caprolactamate, and their derivatives and analogues.
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