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Proton conduction material and method of manufacturing the same

机译:质子传导材料及其制造方法

摘要

A proton conduction material having high proton conductivity and exhibiting high reactive gas permeability regardless of the percentage of water content is provided. This proton conduction material consists of a polymer material whose molecular structure has a strong acid functional group. This polymer material consists of a polymer of a mixture of a monomer having an end structure expressed by a formula (1) or a vinyl radical and a monomer expressed by a formula (2). embedded image;A strong acid functional group is included in the structure of both the monomers. It is to be noted herein that R1, R2, R3, R4, R5 and R6 represent a hydrocarbon radical, a fluoro-substituted hydrocarbon radical, or a trimethylsiloxy radical. Because introduction of a structure in which a hydrocarbon radical is bonded to silicon weakens interaction and causes bulkiness, gaps are created among atoms. If the number of the gaps among the atoms increases, the diffusion coefficient of reactive gases increases. As a result, permeability of the reactive gases can be enhanced.
机译:提供了具有高质子传导性并且表现出高反应性气体渗透性而与水含量的百分比无关的质子传导材料。该质子传导材料由分子结构具有强酸官能团的高分子材料构成。该聚合物材料由具有由式(1)表示的末端结构的单体或乙烯基的混合物与由式(2)表示的单体的混合物构成。 <图像alt =“嵌入式图像” file =“ US06995225-20060207-C00001.GIF” he =“ 36.49mm” imgContent =“ chem” imgFormat =“ GIF” wi =“ 48.26mm” /> ;两种单体的结构中均包含强酸官能团。在此应注意,R 1,R 2,R 3,R 4,R 5和R 6表示烃基,氟取代的烃基或三甲基甲硅烷氧基。由于引入其中烃基与硅键合的结构会削弱相互作用并引起体积大,因此在原子之间会产生间隙。如果原子间的间隙数增加,则反应气体的扩散系数增加。结果,可以提高反应气体的渗透性。

著录项

  • 公开/公告号US6995225B2

    专利类型

  • 公开/公告日2006-02-07

    原文格式PDF

  • 申请/专利权人 TAKUICHI ARAI;HIROSHI HAMAGUCHI;

    申请/专利号US20030702428

  • 发明设计人 TAKUICHI ARAI;HIROSHI HAMAGUCHI;

    申请日2003-11-07

  • 分类号C08F130/08;

  • 国家 US

  • 入库时间 2022-08-21 21:40:43

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