5 - fosforilaminopirazol Derivatives, method for their preparation, compositions containing pesticides, the use thereof for the manufacture of a product and a method for controlling pests that uses.

摘要

This refers to Derivatives of 5 - foasforilaminopirazol. Processes for their preparation, compositions, and their use to control pests (including insects and Worms).Claim 1: a compound of the formula (1): R1 is cn or csnh2; W Halogen is C - C or - CH3, N; R2 is H, halogen, CH3 or nr8r9; R3 is haloalquilo C1 - 3 to - 3, haloalcoxi C1 or C2; R4 is H, alquenilo - 6 haloalquenilo C2 - 6, 6 - haloalquinilo alquinilo C2, C2 - C3 - 7 6, cycloalkyl alkyl -, CO2 - C1 6 CO2 alquenilo C3 - 6, 6 - alquinilo C3 - CO2, CO2 - (CH2) cor11 MR10, or so2r12,C1 - 6 or alkyl unsubstituted or substituted with one or more selected from the group formed by radical Halogen, alkoxy haloalcoxi C1 C1 - 6, - 6, - 6 haloalqueniloxi alqueniloxi C3, C3 - 6 - 6, alquiniloxi C3, C3 C3 haloalquiniloxi cycloalkyl - 6, - 7, S (OR) pr13, NS, Oh, cor11, NO2, nr8r9, S (OR) PR10 or10, and CO2 R11; X is o or s; R5 and R6 are each independently alquenilo haloalquenilo C3 C3 - 6 - 6Alquinilo haloalquinilo C3 C3 - 6, - 6, - 7 pp. ISBN cycloalkyl, R10, R14, NH2, Oh, alkyl and alkyl - 6 C1, C1 or C3 yalquenilo - 6 - 6, where the last three Radicals mentioned above are not replaced or substituted with one or more selected from the group consisting of halogen Radicals, 6 - alkoxy C1, haloalc Oxy - 6 alqueniloxi C1, C3 C3 haloalqueniloxi - 6, - 6, - 6 haloalquiniloxi alquiniloxi C3, C3 - 6Cycloalkyl C3 - 7, S (OR) pr13, CN, NO2, Oh, cor15, nr8r9, or10, R10, R14 and co2r15; or each and cycloalkyl - C3 - 7 unsubstituted or substituted with one or more selected from the group formed by radical Halogen, alkyl haloalquilo C1 and C1 - 6 - 6 or is Each One and - R10 or R5 and R6; together with the Atom United Phosphorus can form a Ring of 56 or 7 members saturated or unsaturated which is not replaced or radical is substituted with one or more selected from the group formed by Halogen, alkyl haloalquilo C1 and C1 - 6 - 6; and is o, s or nr8; R7 and R13 are each independently alkyl haloalquilo C1 C1 - 6 - 6, alquenilo C2 - 6, halo Alquenilo C2 - 6, 6 - haloalquinilo alquinilo C2 or C2 - 6; R8 and R9 are each independently h,Rent haloalquilo C1 C1 - 6, - 6, - 6 haloalquenilo alquenilo C3, C3 C3 alquinilo - 6, - 6, - 7 cicloalquil C3 or cycloalkyl alkyl C1 - C3 - 7 - 6; or with the R8 and R9 n Atom together form a Ring of 5 or 6 members which optionally saturated contains a heteroatom in The Ring which additional Select o, s and NWhere the ring is not replaced or radical is substituted with one or more selected from the group formed by Halogen, alkyl haloalquilo C1 and C1 - 6 - 6; R10 is unsubstituted or substituted phenyl radical with one or more selected from the group formed by Halogen, alkyl of C1 - 6, haloalquilo C1 - 6, 6 - alkoxy haloalcoxi C1, C1 - 6 ns, NO2, S (OR) pr15, cor8, cor16, conr8r9, so2nr8r9,Nr8r9 and Oh; R11 is C1 - 6 h, alkyl, cycloalkyl haloalquilo C1 - C3 - 6, 7, cicloalquil C1 C3 alkyl - 6 - 7 - (CH2) or cycloalkyl QR10; R12 is alquenilo C3 C3 - 7 - 6, 6 - alquinilo haloalquenilo C3, C3 C3 - 6 - 6, haloalquinilo R10 or alkyl radical C1 - 6 whose last mentioned is not replaced or replacement Radical left with one or more selected from the group formed by Halogen, alkoxy C1 - 6Haloalcoxi C1 - C3 - alqueniloxi 6, 6, 6 alquiniloxi haloalqueniloxi C3, C3 - 6, haloalquiniloxi cycloalkyl C3 C3 - 6, - 7, S (OR) pr13, CN, NO2, Oh, cor15, nr11cor13, nr11so2r13, conr8r11, nr8r11 or10, and co2r15; heterociclilo R14 is replaced or not replaced with one or more selected from the group of radical Formed by c1-4 alkyl, halogen, haloalquilo c1-4, haloalcoxi C1 - 4 NS, CO2, NO2, alkyl C1 - 6S (o) pr15, oh and oxo; R15 is alkyl or haloalquilo C1 C1 - 6 - 6; R16 is unsubstituted or substituted phenyl radical with one or more selected from the group formed by Halogen, alkyl of C1 - 6, 6 - alkoxy haloalquilo C1, C1 - 6 - 6, haloalcoxi C1 CN; No2.S (o) pr15 and nr8r9; n and P are each independently 0, 1 or 2; M and q are each independently 0 OR 1; and in each heterociclilo Radicals mentioned above is regardless a Heterocyclic radical with 3 to 7 Atoms in the ring and 1, 2 or 3 heteroatoms in the ring. Onados group consisting of N, o and S; Pesticide or its acceptable Salt.Claim 2: a process for the preparation of a compound of the formula (1) or its Salt as defined in any of claims 1 to 5, which includes: (a) where a is cn and R1, R2, R3, R4, R5, R6, R7, W, X and N are defined as in claim 1, by reacting a compound of L Formula (2); where the different values are as defined in claim 1,A compound of formula (3), R5, R6, and x are as defined in claim 1, and L is a leaving Group; or (b) where R1 is CN, and R2, R3, R4, R5, R7, W, X and N are as defined in claim 1 nr8r9 R6, and, Oh,And alkyl - 6 or - C1 and C3 6 alquenilo whose last 2 Radicals mentioned above are not replaced or substituted with one or more selected from the group formed by radical Halogen, alkoxy haloalcoxi C1 C1 - 6, - 6, - 6 haloalqueniloxi alqueniloxi C3, C3 - 6, 6 - haloalquiniloxi alquiniloxi C3, C3 - 6, CIC Loalquilo C3 - 7, S (OR) pr13, CN, NO2, Oh, cor15, nr8r9, or10 R10R14 and co2r15; or are each and cycloalkyl - C3 - 7 unsubstituted or substituted with one or more selected from the group formed by radical Halogen, alkyl haloalquilo C1 and C1 - 6 - 6; or are each and R10, reacting a compound of formula (4 or group where L1 is outgoing s and other values On as defined in claim 1,A compound of the formula (5) R6 h; where R6 are as defined in claim 1; or (c) where R1 is CN, and R2, R3, R4, R5, R7, W, X and N are as defined in claim 1, and R6 is nr8r9, Oh, and alkyl - 6 or - C1 and C3 6 alquenilo whose last 2 Radicals mentioned above are not replaced S or are replaced with one or more selected from the group consisting of halogen Radicals,6 - alkoxy haloalcoxi C1, C1 - C3 - alqueniloxi 6, 6, 6 alquiniloxi haloalqueniloxi C3, C3 - 6, haloalquiniloxi cycloalkyl C3 C3 - 6, - 7, S (OR) pr13, CN, NO2, Oh, cor15, nr8r9 or10, R10, R14, and each one is and co2r15; or cycloalkyl - C3 - 7 unsubstituted or substituted with one or more selected Radicals of Grup Formed by alkyl or Halogen, C1 and C1 haloalquilo - 6, - 6, and - are each R10Reacting a compound of formula (6): where L1 is a leaving Group, and the other values are as defined in claim 1, a compound of the formula (2) as defined above, to give the compound corresponding to formula (4), followed by reaction with a com Since the formula (5) as defined above; or (d) where R1 is CN, and R2, R3, R4, R7,W, X and N are as defined in claim 1, and R5 and R6 are each independently nr8r9, Oh, and alkyl - 6 or - C1 and C3 6 alquenilo whose last 2 Radicals mentioned above are not replaced or substituted with one or more selected from the group formed by radical Halogen, alkoxy Haloalcoxi C1 - 6, C! - 6, 6 - haloalqueniloxi alqueniloxi C3, C3 - 6, 6 - haloalquiniloxi alquiniloxi C3, C3 - 6Cycloalkyl C3 - 7, S (OR) pr13, CN, NO2, Oh, cor15, nr8r9, or10, R10, R14 and co2r15, or are each and cycloalkyl - C3 - 7 unsubstituted or substituted with one or more selected from the group formed by radical Halogen, alkyl haloalquilo C1 and C1 - 6 - 6; or are each and R10, reacting a Compound The Formula (7), where L1 is a leaving Group,And the other values are as defined in claim 1, a compound of the formula 8 R5 or R6 - formula h, 9 h, where R5 and R6 are each independently nr8r9, Oh, and alkyl - 6 or - C1 and C3 6 alquenilo whose last 2 Radicals mentioned above are not replaced or are replaced with a Or more radical selected from the group formed by Halogen, alkoxy haloalcoxi C1 C1 - 6 - 6Alqueniloxi haloalqueniloxi C3 C3 - 6, - 6, - 6 alquiniloxi C3, C3 C3 haloalquiniloxi cycloalkyl - 6, - 7, S (OR) pr13, CN, NO2, Oh, cor15, nr8r9, or10, R10, R14 and co2r15; or are each and cycloalkyl - C3 - unsubstituted or substituted with 7 one or More selected from the group consisting of halogen Radicals, alkyd ILO haloalquilo C1 and C1 - 6 - 6, and - R10 or are each; or (e) where R1 is CN, and R2, R3, R4, R7, WX and N are as defined in claim 1; and R5 and R6 are each independently nr8r9, Oh, and alkyl C! - 6 - 6 or - alquenilo and C3 Radicals whose last 2 mentioned above are not replaced or substituted with one or more selected from the group formed by radical Halogen, alkoxy haloalcoxi C1 C1 - 6, - 6, - 6 alquiniloxi alqueniloxi C3, C3 - 6, haloalquiniloxi cycloalkyl C3 C3 - 6, - 7.S (o) pr13, CN, NO2, Oh, cor15, nr8r9, or10, R10, R14 and co2r15; or are each and cycloalkyl - C3 - 7 unsubstituted or substituted with one or more selected from the group formed by radical Halogen, alkyl haloalquilo C1 and C1 - 6 - 6; or each and - R10, reacting a compound of formula (10) Where L1 is a leaving Group with a compound of formula (2) as defined above,The Compound corresponding to formula (7) as defined above, followed by reaction with a compound of formula (8) or (9) as defined above; (f) where R1 or R2 is nr8r9 is CN, and other values are as defined in claim 1 make reac The Compound of the formula (1) wherein R2 is Halogen,A compound of the formula (11) or its Salt r8r9n - H where R8 and R9 are as defined in claim 1; or (g) where R1 is csnh2, and other values are as defined in claim 1, reacting The Compound corresponding to formula (1) wherein R1 is cn with a D, HYDROSULFIDE And alkali or Alkaline Earth Metal, or with H2S in the presence of an organic base.Or with the Reagent ph2ps2; or (H) where R1 is csnh2, and other values are as defined in claim 1, reacting The Compound corresponding to formula (1) wherein R1 is CN, with a bis (trialquilsilil) SULFIDE in the presence of a base; or (i) where R1 and