首页> 外国专利> Method for production of Bhutan. The 1, 4 diol 4-DOIL BUTANE-1, butyrolactone BUTYROLACTONE and Hydrwfywran TETRAHYDROFURAN

Method for production of Bhutan. The 1, 4 diol 4-DOIL BUTANE-1, butyrolactone BUTYROLACTONE and Hydrwfywran TETRAHYDROFURAN

机译:生产不丹的方法。 1,4二醇4-DOIL BUTANE-1,丁内酯BUTYROLACTONE和Hydrwfywran TETRAHYDROFURAN

摘要

The invention relates to a method for describing how to produce at least one C4 compound from Bhutan. One step hydrogenation of tetrahydrofuran and tetrahydrofuran in non hydride gas phaseIn the presence of maleic anhydride, the catalyst for maleic acid hydrogenation has the property of heterogeneous hydrogenation. This includes the following aspects: contact with maleic anhydride, water vapor and carbon oxide in the absorption zone of high boiling organic solventMaleic anhydride with a boiling point of at least three degrees at air pressure results in the formation of a maleic anhydride solution in an organic solvent with a high boiling point. Loss from absorption zoneIn a high-boiling solvent with a gaseous stream containing hydrogen. Together, it leads to the separation (removal) of maleic anhydride from it and the formation of a vapor duct, including hydrogen and maleic hydride. (D) Touching a substance from the vapor stream from step (e) in the hydrogenation regionUnder hydrogenation conditions with an isotropic hydrogenation catalyst leading to the conversion of the maleic anhydride to at least one C4 compound selected from Bhutan - 1, 4 diol, γ - butyrolactone and tetrahydrofuran, (e) recovery of a duct product from the hydrogenation region containing the said C4 compound .
机译:本发明涉及描述如何从不丹生产至少一种C4化合物的方法。在非氢化物气相中一步氢化四氢呋喃和四氢呋喃在马来酸酐存在下,用于马来酸氢化的催化剂具有非均相氢化的性质。这包括以下方面:在高沸点有机溶剂的吸收区中与马来酸酐,水蒸气和碳氧化物接触在空气压力下沸点至少为3度的马来酸酐导致在有机溶剂中形成马来酸酐溶液。高沸点的溶剂。来自吸收区的损失在高沸点溶剂中以及含有氢气的气态物流。一起导致从中分离(除去)顺丁烯二酸酐,并形成蒸气管道,包括氢气和顺丁烯二酸酐。 (D)在加氢条件下,用各向同性加氢催化剂,使步骤(e)的蒸气流中的物质与加氢区域接触,从而使马来酸酐转化为至少一种选自不丹-1、4二醇,γ的C4化合物。 -丁内酯和四氢呋喃,(e)从含有所述C 4化合物的氢化区域回收导管产物。

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