首页> 外国专利> FLUORINE-MODIFIED POLYURETHANE RESINS CONTAINING ONE OR TWO CONSTITUENTS, METHOD FOR THE PRODUCTION THEREOF, AND USE OF THE SAME

FLUORINE-MODIFIED POLYURETHANE RESINS CONTAINING ONE OR TWO CONSTITUENTS, METHOD FOR THE PRODUCTION THEREOF, AND USE OF THE SAME

机译:包含一种或两种成分的氟改性的聚氨酯树脂,其生产方法和用途

摘要

The invention relates to a fluorine-modified polyurethane resin containing one or two constituents and having improved surface properties. Said resin can be obtained by a) producing a fluorine-modified polyurethane prepolymer with free isocyanate groups or free amino groups and/or hydroxyl groups or a fluorine-modified polyol mixture with free hydroxyl groups (binding agent), and by b) producing a fluorine-modified polyurethane resin with a polymer-related fluorine content of between 1 and 4 wt. % in the entire system. According to the invention, the fluorine-modified polyurethane prepolymer from step a3) is reacted, in the event of a single-constituent application, with atmospheric humidity, or in the event of a double-constituent application, the fluorine-modified polyurethane prepolymer or polyol mixture (binding agent) is reacted with a cross-linking constituent (D) (hardener) and a formulation constituent (F), (ii) optionally in the presence of a solvent constituent (L)(iii) and a catalyst. By using suitable fluorinated macromonomers in the inventive single or double-constituent polyurethane resins, hard coating systems or surfaces with very low surface tensions and very high contact angles can be produced. Said polyurethane resins also have a significantly reduced soiling tendency in relation to prior art.
机译:本发明涉及一种氟改性的聚氨酯树脂,其包含一种或两种成分并具有改善的表面性能。所述树脂可以通过以下方法获得:a)生产具有游离异氰酸酯基或游离氨基和/或羟基的氟改性聚氨酯预聚物,或具有游离羟基的氟改性的多元醇混合物(粘合剂),以及b)生产a与聚合物有关的氟含量在1-4 wt%之间的氟改性聚氨酯树脂。在整个系统中的百分比。根据本发明,在单组分施用的情况下,将步骤a3)的氟改性的聚氨酯预聚物与大气湿度反应,或者在双组分施用的情况下,将步骤a3)的氟改性的聚氨酯预聚物与氟改性的聚氨酯预聚物进行反应。多元醇混合物(粘合剂)与交联组分(D)(硬化剂)和配方组分(F)反应,(ii)任选在溶剂组分(L)(iii)和催化剂存在下进行。通过在本发明的单或双组分聚氨酯树脂中使用合适的氟化大分子单体,可以制得具有非常低的表面张力和非常高的接触角的硬涂层体系或表面。相对于现有技术,所述聚氨酯树脂还具有明显减少的污染趋势。

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