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Method of Preparing Low-costed AS Resin with Good Heat Resistance

机译:一种低成本,耐热性好的AS树脂的制备方法

摘要

The method for producing a superior heat resistance with low cost AS resin according to the present invention is deionized water, primary dispersant and a secondary dispersant comprising: a first step of mixing were charged into a reactor, 60 to 80 parts by weight of alpha-methyl styrene monomer, acrylonitrile monomer, and 20 to 40 parts by weight of the two types of peroxide-based polymerization initiator continuously to the reactor 0.1 to 1 parts by weight after the second step of a batch input, and the degree of polymerization while maintaining the temperature of the reactor to 60~90 be suspended until the polymerization reaction reached 70-85%, while raising the temperature of the reactor to 100~125 characterized in that it comprises a third step of the suspension polymerization reaction. At this time, the two kinds of the peroxide-based polymerization initiator is preferably a functional group having the 10-hour half-life temperatures are different from each other, the two kinds of the peroxide-based polymerization initiator are each half-life temperature of the initiator and the half-life temperature of 60~80 The 80~120 and the initiator, it is more preferable that each dose is 0.2 to 0.6 parts by weight of 0.05 to 0.3 parts by weight.
机译:根据本发明的用低成本AS树脂生产优异的耐热性的方法是去离子水,一级分散剂和二级分散剂,其包括:将混合的第一步加入反应器中,将60-80重量份的α-在第二步分批输入后,将0.1至1重量份的甲基苯乙烯单体,丙烯腈单体和20至40重量份的两种类型的过氧化物基聚合引发剂连续0.1至1重量份地连续加入反应器中,同时保持聚合度将反应器的温度升至60〜90℃,直至聚合反应达到70〜85%,同时将反应器的温度升至100〜125℃,其特征在于,它包括悬浮聚合反应的第三步。此时,两种过氧化物类聚合引发剂优选为具有10小时半衰期温度互不相同的官能团,两种过氧化物类聚合引发剂分别为半衰期温度引发剂的半衰期温度为60〜80,引发剂的半衰期为80〜120,引发剂的半衰期温度更优选为0.05〜0.3重量份的0.2〜0.6重量份。

著录项

  • 公开/公告号KR100576322B1

    专利类型

  • 公开/公告日2006-05-03

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20030098932

  • 发明设计人 송정훈;장정호;하두한;

    申请日2003-12-29

  • 分类号C08F212/10;

  • 国家 KR

  • 入库时间 2022-08-21 21:23:52

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