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Activation method of titanium silicalite and its use in oxidation processes with hydrogen peroxide

机译:钛硅沸石的活化方法及其在双氧水氧化工艺中的应用

摘要

The present invention relates to a method of using hydrogen peroxide as a catalyst 1 in an aqueous medium, by activating in the presence of an anionic species containing precursor or fluoride of the fluoride ion, to improve the catalytic performance of titanium silicalite of formula will be. ; 1 is an active catalyst for oxidation of organic substances with hydrogen peroxide, in particular, it is especially useful for the oxidation reaction of the epoxidation reaction and a nitrification reaction of the compounds of the hydroxy aromatic compound, an olefin compound.
机译:本发明涉及一种在水性介质中使用过氧化氢作为催化剂1的方法,该方法是通过在含有氟离子的前体或氟化物的阴离子物质的存在下进行活化,以提高下式的钛硅沸石的催化性能。 。 ;图1的化合物是用过氧化氢氧化有机物的活性催化剂,特别是对于羟基芳族化合物即烯烃化合物的环氧化反应的氧化反应和硝化反应特别有用。

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