METHOD FOR IMPROVING THE TEMPERATURE loss of mobility of hydrocarbons obtained during the Fischer-Tropsch catalyst is used based on zeolite ZBM-30

摘要

1. method u0443u043bu0443u0447u0448u0435u043du0438u00a0 temperature loss of mobility u0441u044bu0440u044cu00a0 fischer tropsch derived method, which u043fu0440u0438u0432u043eu0434u0438u0442u0441u00a0 u043eu0431u0440u0430u0431u0430u0442u044bu0432u0430u0435u043cu043eu0435 raw material in contact with the catalyst. containing at least one u0446u0435u043eu043bu0438u0442 ZBM - 30, u0442u0440u0438u044du0442u0438u043bu0435u043du0442u0435u0442u0440u0430u043cu0438u043du0430 novo in the presence of at least one u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 - u0434u0435u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 element and extremely in least one u043du0435u043eu0440u0433u0430u043du0438u0447u0435u0441u043au0443u044e porous matrix.;2. method for 1, in which u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 - u0434u0435u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 element selected from elements of groups and group viii of the periodic system of elements VIB.;3. method for 2, which u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 - u0434u0435u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 element group VIB u00a0u0432u043bu00a0u0435u0442u0441u00a0 u043cu043eu043bu0438u0431u0434u0435u043du043eu043c and / or wolfram.;4. method for 1, in which u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 - u0434u0435u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 element of viii group noble metal u00a0u0432u043bu00a0u0435u0442u0441u00a0 viii group.;5. method for 1, in which u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 - u0434u0435u0433u0438u0434u0440u0438u0440u0443u044eu0449u0438u0439 element of viii group u00a0u0432u043bu00a0u0435u0442u0441u00a0 a platinum and / or palladium.;6. way on one of the u043fu043f.1 - 5, in which the processed raw material contains at least 50% of the compounds. u043au0438u043fu00a0u0449u0438u0445 above 340C.;7. way on one of the u043fu043f.1 - 5, in which the operating mode: the temperature response from 200 to 450C, pressure from 0.1 to 25 mpa, the long time discharge (u043eu0431.u043eu0431.u0447., u0432u044bu0440u0430u0436 u0435u043du043du044bu0439 volume u0441u044bu0440u044cu00a0, u043fu0440u043eu0445u043eu0434u00a0u0449u0438u0439 in unit volume of the catalyst in an u0441u043eu0441u0442u0430u0432u043bu00a0u0435u0442 from about 0.05 to about 30 h - 1.;8. way on one of the u043fu043f.1 - 5, in which the raw material is first u043fu043eu0434u0432u0435u0440u0433u0430u0435u0442u0441u00a0 u0433u0438u0434u0440u043eu0438u0437u043eu043cu0435u0440u0438u0437u0430u0446u0438u0438 - u0433u0438u0434u0440u043eu043au043eu043du0432u0435u0440u0441u0438u0438.;9. method for point 9, in which the flow u0432u044bu0445u043eu0434u00a0u0449u0438u0439 stage u0433u0438u0434u0440u043eu0438u0437u043eu043cu0435u0440u0438u0437u0430u0446u0438u0438 - conversion, fully u043fu0440u043eu0432u043eu0434u0438u0442u0441u00a0 fuel in internal phase.;10. way on one of the u043fu043f.1 - 5, in which the u0433u0438u0434u0440u043eu0438u0437u043eu043cu0435u0440u0438u0437u0430u0446u0438u0438 - u0433u0438u0434u0440u043eu043au043eu043du0432u0435u0440u0441u0438u0438 precedes the phase of hydro.;11. way on p.10, in which phase hydro follows the intermediate division.;12. way on one of the u043fu043f.1 - 5, in which the flow u0432u044bu0445u043eu0434u00a0u0449u0438u0439 stage catalytic fuel in internal, at least in part on the catalyst u043fu0440u043eu0432u043eu0434u0438u0442u0441u00a0 hydro.;13.the way in which u0440u0435u0430u043bu0438u0437u0443u044eu0442u0441u00a0 the following stages: u043eu0431u0440u0430u0431u0430u0442u044bu0432u0430u0435u043cu043eu0435 raw materials u0440u0430u0437u0434u0435u043bu00a0u044eu0442 (d1), at least one light fraction 3 with temperature u043au0438u043fu0435u043du0438u00a0 below 380C and edge it least one u0442u00a0u0436u0435u043bu0443u044e fraction 4 (residual fraction), u0443u043au0430u0437u0430u043du043du0430u00a0 u043bu0435u0433u043au0430u00a0 u0444u0440u0430u043au0446u0438u00a0 3, if necessary u0433u0438u0434u0440u0438u0440u043eu0432u0430u043du043du0430u00a0 phase u0433u0438u0434u0440u043eu043eu0431u0440u0430u0431u043eu0442u043au0438 (HDT), u043fu043eu0434u0432u0435u0440u0433u0430u0435u0442u0441u00a0 u0433u0438u0434u0440u043eu0438u0437 u043eu043cu0435u0440u0438u0437u0430u0446u0438u0438 (HISM)u0443u043au0430u0437u0430u043du043du0430u00a0 u0442u00a0u0436u0435u043bu0430u00a0 u0444u0440u0430u043au0446u0438u00a0 4 u043fu043eu0434u0432u0435u0440u0433u0430u0435u0442u0441u00a0 phase u0433u0438u0434u0440u043eu043au0440u0435u043au0438u043du0433u0430 (HCK) in the presence of hydrogen, then u043fu043eu0434u0432u0435u0440u0433u0430u0435u0442u0441u00a0 refining (d2) u0434u043bu00a0 u043fu043eu043bu0443u0447u0435u043du0438u00a0 of at least one u043bu0435u0433u043a oh fraction (13) and at least one u0442u00a0u0436u0435u043bu043eu0439 fraction (10), a mixture obtained by u0433u0438u0434u0440u043eu0438u0437u043eu043cu0435u0440u0438u0437u0430u0446u0438u0438 (HISM), u0444u0440u0430u043au0446u0438u043eu043du0438u0440u0443u044eu0442 (d3) together with at least a part of the le u0433u043au043eu0439 fraction obtained at stage 13, a d2u0434u043bu00a0 u043fu043eu043bu0443u0447u0435u043du0438u00a0 secondary u0434u0438u0441u0442u0438u043bu043bu00a0u0442u043eu0432 having excellent low-temperature quality and / or high cetane number and / or the low allocation of u0437u0430u0433u0440u00a0u0437u043du00a0u044eu0449u0438u0445 prim u0435u0441u0435u0439, u0442u00a0u0436u0435u043bu0443u044e faction u0432u044bu0445u043eu0434u00a0u0449u0443u044e stage d2 are subjected to phase fuel in internal (DWX) u0434u043bu00a0 u043fu043eu043bu0443u0447u0435u043du0438u00a0 after u043eu0442u0434u0435u043bu0435u043du0438u00a0 u043eu0431u0440u0430u0437u043eu0432u0430u0432u0448u0438u0445u0441u00a0 volatile products of liquid u0438u0437u043eu043cu0435u0440u0438u0437u043eu0432 u0430u043du043du044bu0445 products suitable as base lubricants qualityand the way of fuel in internal u00a0u0432u043bu00a0u0435u0442u0441u00a0 manner on one of the u043fu043f.1 - 7.